One-pot synthesis of ZnLaxFe2-xO4 clusters without any template and their possible application in water treatment

被引:30
作者
Zhao, Baobao [1 ]
Nan, Zhaodong [1 ]
机构
[1] Yang Zhou Univ, Coll Chem & Chem Engn, Yangzhou 225002, Peoples R China
关键词
MAGNETIC-PROPERTIES; PHYSICAL-PROPERTIES; FERRITES; SUBSTITUTION; MONODISPERSE; LA3+; NANOPARTICLES; NANOSPHERES; GROWTH; ND3+;
D O I
10.1039/c1jm13406j
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A facile and efficient one-pot solvothermal synthetic route is proposed to fabricate spherical La3+ doped zinc ferrite clusters without any template and surfactant. Numerous nanoparticles are aggregated to form clusters with uniform shape and size. Different values of x in ZnLaxFe2-xO4 induce different magnetic parameters for these clusters. Especially, the maximum of the saturation magnetization of ZnLaxFe2-xO4 clusters is 86 emu g(-1) when x = 0.02. This result is different to those reported, in which the saturation magnetization decreased with La3+ doping. The as-prepared clusters also showed good performance in removal of pollutants like methyl orange from water by adsorption. Different Brunauer-Emmett-Teller (BET) surface areas may induce a different capacity in removal of the pollutant.
引用
收藏
页码:6581 / 6586
页数:6
相关论文
共 43 条
[1]   Enhancement of the physical properties of rare-earth-substituted Mn-Zn ferrites prepared by flash method [J].
Ahmed, M. A. ;
Okasha, N. ;
El-Sayed, M. M. .
CERAMICS INTERNATIONAL, 2007, 33 (01) :49-58
[2]   Structural and electrical studies on La3+ substituted Ni-Zn [J].
Ahmed, MA ;
Ateia, E ;
Salah, LM ;
El-Gamal, AA .
MATERIALS CHEMISTRY AND PHYSICS, 2005, 92 (2-3) :310-321
[3]   A versatile bottom-up assembly approach to colloidal spheres from nanocrystals [J].
Bai, Feng ;
Wang, Dingsheng ;
Huo, Ziyang ;
Chen, Wei ;
Liu, Liping ;
Liang, Xin ;
Chen, Chen ;
Wang, Xun ;
Peng, Qing ;
Li, Yadong .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2007, 46 (35) :6650-6653
[4]   Ferroelectric and ferromagnetic properties of Gd substituted nickel ferrite [J].
Bharathi, K. Kamala ;
Markandeyulu, G. .
JOURNAL OF APPLIED PHYSICS, 2008, 103 (07)
[5]   Magnetic properties in rare-earth substituted spinel Co0.2Zn0.8Fe2-xRExO4 (RE=Dy, Ho and Er, x=0.05) [J].
Bhowmik, RN ;
Ranganathan, R .
JOURNAL OF ALLOYS AND COMPOUNDS, 2001, 326 (1-2) :128-131
[6]   Monodisperse Platinum Nanospheres with Adjustable Diameters from 10 to 100 nm: Synthesis and Distinct Optical Properties [J].
Bigall, Nadja C. ;
Haertling, Thomas ;
Klose, Markus ;
Simon, Paul ;
Eng, Lukas M. ;
Eychmueller, Alexander .
NANO LETTERS, 2008, 8 (12) :4588-4592
[7]   Self-assembly of nanoparticles into structured spherical and network aggregates [J].
Boal, AK ;
Ilhan, F ;
DeRouchey, JE ;
Thurn-Albrecht, T ;
Russell, TP ;
Rotello, VM .
NATURE, 2000, 404 (6779) :746-748
[8]   Designing PbSe nanowires and nanorings through oriented attachment of nanoparticles [J].
Cho, KS ;
Talapin, DV ;
Gaschler, W ;
Murray, CB .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (19) :7140-7147
[9]   Single-crystal-like hematite colloidal nanocrystal clusters: synthesis and applications in gas sensors, photocatalysis and water treatment [J].
Fang, Xiao-Liang ;
Chen, Cheng ;
Jin, Ming-Shang ;
Kuang, Qin ;
Xie, Zhao-Xiong ;
Xie, Su-Yuan ;
Huang, Rong-Bin ;
Zheng, Lan-Sun .
JOURNAL OF MATERIALS CHEMISTRY, 2009, 19 (34) :6154-6160
[10]   Synthesis, characterization and magnetic properties of La3+ added Mg-Cd ferrites prepared by oxalate co-precipitation method [J].
Gadkari, A. B. ;
Shinde, T. J. ;
Vasambekar, P. N. .
JOURNAL OF ALLOYS AND COMPOUNDS, 2011, 509 (03) :966-972