3D coordination polymers with vanadyl fragments and alkaline earth metal ions

被引：19

作者：

Bazhina, E. S. ^{[1
]}

Nikiforova, M. E. ^{[1
]}

Aleksandrov, G. G. ^{[1
]}

Minin, V. V. ^{[1
]}

Efimov, N. N. ^{[1
]}

Sidorov, A. A. ^{[1
]}

Novotortsev, V. M. ^{[1
]}

Eremenko, I. L. ^{[1
]}

机构：

[1] Russian Acad Sci, NS Kurnakov Inst Gen & Inorgan Chem, Moscow 119991, Russia

来源：

RUSSIAN CHEMICAL BULLETIN | 2011年 / 60卷 / 05期

基金：

俄罗斯基础研究基金会;

关键词：

oxovanadium(IV); heterometallic complexes; cyclopropane-1,1-dicarboxylic acid; X-ray diffraction analysis; ESR spectroscopy; COMPLEXES; OXOVANADIUM(IV);

D O I：

10.1007/s11172-011-0127-6

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reactions of vanadyl sulfate VOSO(4)center dot 3H(2)O with barium or strontium cyclopropane-1,1-dicarboxylate (MCpdc, M = Ba, Sr, H(2)Cpdc = C(3)H(4)(COOH)(2)) afforded the polymeric heterometallic complexes {[(H(2)O)(8)Ba(2)(VO)(2)(Cpdc)(4)]center dot 2H(2)O}n (1) and {[(H(2)O)(6)Sr(VO)(Cpdc)(2)]}n (2), respectively. These complexes differ in the binding mode of mononuclear vanadyl fragments with alkaline earth metal ions. Coordination polymers 1 and 2 were characterized by ESR spectroscopy.

引用

页码：797 / 802

页数：6

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