Highly selective reactions of C60Cl6 with thiols for the synthesis of functionalized [60]fullerene derivatives

被引：62

作者：

Khakina, Ekaterina A. ^{[1
]}

Yurkova, Anastasiya A. ^{[1
]}

Peregudov, Alexander S. ^{[2
]}

Troyanov, Sergey I. ^{[3
]}

Trush, Vyacheslav V. ^{[4
]}

Vovk, Andrey I. ^{[4
]}

Mumyatov, Alexander V. ^{[1
]}

Martynenko, Vyacheslav M. ^{[1
]}

Balzarini, Jan ^{[5
]}

Troshin, Pavel A. ^{[1
]}

机构：

[1] IPCP RAS, Chernogolovka 141432, Russia

[2] INEOS RAS, Moscow 119991, Russia

[3] Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119991, Russia

[4] Natl Acad Sci Ukraine, Inst Bioorgan Chem & Petrochem, UA-02660 Kiev 94, Ukraine

[5] Catholic Univ Louvain, Rega Inst Med Res, B-3000 Louvain, Belgium

来源：

CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 57期

关键词：

FULLERENE DERIVATIVES; CHLOROFULLERENE C60CL6; INHIBITORS;

D O I：

10.1039/c2cc32517a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Chlorofullerene C60Cl6 undergoes highly selective reactions with thiols forming compounds C-60[SR](5)H with high yields. These reactions open up straightforward synthetic routes to many functionalized fullerene derivatives, e. g. water-soluble compounds showing interesting biological activities.

引用

页码：7158 / 7160

页数：3

共 28 条

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