Enhancement of Visible-Light Photocatalysis by Coupling with Narrow-Band-Gap Semiconductor: A Case Study on Bi2S3/Bi2WO6

被引:423
作者
Zhang, Zhijie [1 ]
Wang, Wenzhong [1 ]
Wang, Lu [1 ]
Sun, Songmei [1 ]
机构
[1] Chinese Acad Sci, Shanghai Inst Ceram, State Key Lab High Performance Ceram & Superfine, Shanghai 200050, Peoples R China
基金
中国国家自然科学基金;
关键词
Bi2S3/Bi2WO6; composite; photocatalysis; heterojunction; phenol; DEGRADATION; BI2WO6; HYDROGEN; TIO2; ABSORPTION; SULFIDE; AGENT; CDS;
D O I
10.1021/am2017199
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
To overcome the drawback of low photocatalytic efficiency brought by electron hole recombination and narrow photoresponse range, we designed a novel Bi2S3/Bi2WO6 composite photocatalyst. The composite possesses a wide photoabsorption until 800 nm, which occupies nearly the whole range, of the visible light Compared with bare Bi2WO6, the Bi2S3/Bi2WO6 composite exhibits significantly enhanced photocatalytic activity for phenol degradation Under visible light irradiation. On the basis of the calculated energy band positions, the mechanism of enhanced photocatalytic activity was proposed. The present study provides a new strategy to design composite materials with enhanced photocatalytic performance.
引用
收藏
页码:593 / 597
页数:5
相关论文
共 36 条
  • [1] Visible Light Responsive Pristine Metal Oxide Photocatalyst: Enhancement of Activity by Crystallization under Hydrothermal Treatment
    Amano, Fumiaki
    Yamakata, Akira
    Nogami, Kohei
    Osawa, Masatoshi
    Ohtani, Bunsho
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (52) : 17650 - +
  • [2] Visible-light photocatalysis in nitrogen-doped titanium oxides
    Asahi, R
    Morikawa, T
    Ohwaki, T
    Aoki, K
    Taga, Y
    [J]. SCIENCE, 2001, 293 (5528) : 269 - 271
  • [3] Synthesis of a highly ordered single-crystalline Bi2S3 nanowire array and its metal/semiconductor/metal back-to-back Schottky diode
    Bao, Haifeng
    Li, Chang Ming
    Cui, Xiaoqiang
    Gan, Ye
    Song, Qunliang
    Guo, Jun
    [J]. SMALL, 2008, 4 (08) : 1125 - 1129
  • [4] Self-templated synthesis of nanoporous CdS nanostructures for highly efficient photocatalytic hydrogen production under visible
    Bao, Ningzhong
    Shen, Liming
    Takata, Tsuyoshi
    Domen, Kazunari
    [J]. CHEMISTRY OF MATERIALS, 2008, 20 (01) : 110 - 117
  • [5] Bi2S3/TiO2 and CdS/TiO2 heterojunctions as an available configuration for photocatalytic degradation of organic pollutant
    Bessekhouad, Y
    Robert, D
    Weber, J
    [J]. JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2004, 163 (03) : 569 - 580
  • [6] Hydrogen photoproduction from hydrogen sulfide on Bi2S3 catalyst
    Bessekhouad, Y
    Mohammedi, M
    Trari, M
    [J]. SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2002, 73 (03) : 339 - 350
  • [7] Cross-Linking Bi2S3 Ultrathin Nanowires: A Platform for Nanostructure Formation and Biomolecule Detection
    Cademartiri, Ludovico
    Scotognella, Francesco
    O'Brien, Paul G.
    Lotsch, Bettina V.
    Thomson, Jordan
    Petrov, Srebri
    Kherani, Nazir P.
    Ozin, Geoffrey A.
    [J]. NANO LETTERS, 2009, 9 (04) : 1482 - 1486
  • [8] Photocatalytic properties of nanosized Bi2WO6 catalysts synthesized via a hydrothermal process
    Fu, Hongbo
    Zhang, Liwu
    Yao, Wenqing
    Zhu, Yongfa
    [J]. APPLIED CATALYSIS B-ENVIRONMENTAL, 2006, 66 (1-2) : 100 - 110
  • [9] Time-resolved photoluminescence of particulate TiO2 photocatalysts suspended in aqueous solutions
    Fujihara, K
    Izumi, S
    Ohno, T
    Matsumura, M
    [J]. JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2000, 132 (1-2) : 99 - 104
  • [10] Enhanced photocatalytic activity of electrosynthesised tungsten trioxide-titanium dioxide bi-layer coatings under ultraviolet and visible light illumination
    Georgieva, J.
    Armyanov, S.
    Valova, E.
    Poulios, I.
    Sotiropoulos, S.
    [J]. ELECTROCHEMISTRY COMMUNICATIONS, 2007, 9 (03) : 365 - 370