Efficient generation of stable adducts of Si(II) dihydride using a donor-acceptor approach

被引：96
作者：
Al-Rafia, S. M. Ibrahim [1 ]
Malcolm, Adam C. [1 ]
McDonald, Robert [1 ]
Ferguson, Michael J. [1 ]
Rivard, Eric [1 ]
机构：
[1] Univ Alberta, Dept Chem, Edmonton, AB T6G 2G2, Canada
来源：
CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 09期
基金：
加拿大自然科学与工程研究理事会; 加拿大创新基金会;
关键词：
N-HETEROCYCLIC CARBENE; BASE-STABILIZED DICHLOROSILYLENE; TRANSITION-METAL-COMPLEXES; RHODIUM(I) COMPLEXES; SILICON(II) HYDRIDE; SILYLENE; REACTIVITY; CHEMISTRY; HYDROSILYLATION; LIGANDS;
D O I：
10.1039/c2cc17101e
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A stable Si(II) dihydride complex, IPr center dot SiH(2)center dot BH(3) (IPr = [(HCNDipp)(2)C:]; Dipp = 2,6-(i)Pr(2)C(6)H(3)), was synthesized and preliminary reactivity involving this source of encapsulated silylene is reported.
引用
收藏
页码：1308 / 1310
页数：3
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