Exploration of O-N-S heteroatom self-doped mesoporous activated carbon derived from Datura stramonium seed pods as a potential electrode for supercapacitor application

被引:9
作者
Subramanian, Dhinesh [1 ]
Raju, Gobi [1 ]
Palanivel, Baskaran [2 ]
Al-Zaqri, Nabil [3 ]
Hossain, Md Shahadat [4 ]
机构
[1] Arignar Anna Govt Arts Coll, PG & Res Dept Phys, Namakkal 02, Tamil Nadu, India
[2] Kings Engn Coll, Dept Phys, Sriperumbudur 602117, Tamil Nadu, India
[3] King Saud Univ, Coll Sci, Dept Chem, POB 2455, Riyadh 11451, Saudi Arabia
[4] Utsunomiya Univ, Grad Sch Engn, Dept Innovat Syst Engn, Yoto 7-1-2, Utsunomiya, Tochigi 3218585, Japan
关键词
Activated carbon; Porosity; Datura stramonium; Heteroatom doping; HIGH-SURFACE-AREA; POROUS CARBON; HIGH-ENERGY; PERFORMANCE; NITROGEN; FABRICATION; SULFUR; OXIDE; GRAPHENE; BIOMASS;
D O I
10.1007/s11581-022-04464-z
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Bio-derived carbon with distinctive electrical conductivity, electrochemical property, and surface chemistry plays a vital role in the field of energy storage applications. In present work, activated carbon (AC) from D. stramonium seed pod in a cost-effective manner and the electrochemical properties were improved by self-doping of heteroatoms (O, N, S). The 1 M of KOH-induced, O-N-S-doped AC possesses high surface area of 1390 m(2)/g, 3D-interconnected network-like structure. The O-N-S-doped bio-derived AC activated by 1 M of KOH electrode exhibits specific capacitance of 665.8 F/g at 5 mV/s in three-electrode system and 166.6 F/g at 5 mV/s in supercapacitor (SC) device. The cyclic stability of Z3 was found to be 65% for 5000 cycles in three-electrode systems and 79.07% remains after 1000 cycles in a two-electrode device. The fabricated SC device delivers high energy density of 29.25 Wh/kg at a power density of 2700 W/kg.
引用
收藏
页码:2363 / 2375
页数:13
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