Silver-catalyzed low-temperature CO isotopic scrambling reaction: 12C16O+13C18O → 12C18O+13C16O

被引：6

作者：

Lagunov, O. ^{[1
]}

Chakarova, K. ^{[1
]}

Hadjiivanov, K. ^{[1
]}

机构：

[1] Bulgarian Acad Sci, Inst Gen & Inorgan Chem, BU-1113 Sofia, Bulgaria

来源：

PHYSICAL CHEMISTRY CHEMICAL PHYSICS | 2012年 / 14卷 / 07期

关键词：

IR SPECTROSCOPY; CARBON-MONOXIDE; ADSORPTION; ZEOLITES; SITES; FTIR; VIBRATIONS; OXIDATION; IONS; AG+;

D O I：

10.1039/c1cp22616a

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

In this paper we report on low-temperature CO isotopic scrambling ((CO)-C-12-O-16 + (CO)-C-13-O-18 -> (CO)-C-12-O-18 + (CO)-C-13-O-16). The reaction proceeds on a commercial silver-exchanged zeolite even at about 100 K and requires an optimal reduction degree of the catalysts.

引用

页码：2178 / 2182

页数：5

共 30 条

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