The first coordination polymer containing a chiral cyclotriphosphazene ligand

被引：39
作者：
Ainscough, Eric W. [1 ]
Brodie, Andrew M. [1 ]
Davidson, Ross J. [1 ]
Otter, Carl A. [1 ]
机构：
[1] Massey Univ, Chem Inst Fundamental Sci, Palmerston North, New Zealand
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2008年 / 11卷 / 02期
关键词：
cyclotriphosphazene; 1,1 '-dioxy-2,2 '-binapthyl; silver(I); chiral coordination polymer;
D O I：
10.1016/j.inoche.2007.12.001
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The preparation and the single crystal X-ray structure of a new chiral ligand, 3,3,5,5-tetrapyridyloxy-1,1-{(R)-1,1'-dioxy-2,2'-binapthyl}cyclotriphosphazene (L-R), is described. L-R reacts with [Ag(MeCN)(4)]PF6 to produce the complex {[AgLR](PF6)center dot Et2O center dot 2MeCN}(n), which was also characterised by X-ray crystallography. The topology of complex is a ID coordination polymer that, in the crystalline structure, consists of two different infinite chains arranged in layers that are approximately orthogonal to each another. (C) 2007 Elsevier B.V. All rights reserved.
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收藏
页码：171 / 174
页数：4
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