Redox-Induced Palladium Migrations that Allow Reversible Topological Changes between Palladium(II) Complexes of Mobius Aromatic [28]Hexaphyrin and Huckel Aromatic [26]Hexaphyrin

被引：51

作者：

Inoue, Mitsunori ^{[1
]}

Osuka, Atsuhiro ^{[1
]}

机构：

[1] Kyoto Univ, Grad Sch Sci, Dept Chem, Sakyo Ku, Kyoto 6068502, Japan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2010年 / 49卷 / 49期

关键词：

aromaticity; hexaphyrins; metalation; palladium; porphyrinoids; EXPANDED PORPHYRINS; CHEMISTRY; METALATION;

D O I：

10.1002/anie.201005334

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Plane twisted: A twisted Möbius aromatic [28]hexaphyrin/Pd II complex and a planar Hückel aromatic [26]hexaphyrin/Pd II complex are reversibly interconvertible by an unprecedented palladium migration through oxidation and reduction (see scheme). The [26]hexaphyrin/PdII complex is a precursor to [26]hexaphyrin hetero-bis(metal) complexes having PdII/CuIII or Pd II/AgIII centers. C gray, N blue, H white, F green, Pd yellow. Copyright © 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：9488 / 9491

页数：4

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