Reaction of 1,3-cyclohexadiene with the Ge(100) surface

被引：34

作者：

Lee, SW

Nelen, LN

Ihm, H

Scoggins, T

Greenlief, CM ^{[1
]}

机构：

[1] Univ Missouri, Dept Chem, Columbia, MO 65211 USA

[2] Univ Texas, NSF Sci & Technol Ctr Synth Growth & Anal Elect M, Austin, TX 78712 USA

来源：

SURFACE SCIENCE | 1998年 / 410卷 / 2-3期

基金：

美国国家科学基金会;

关键词：

1,3-cyclohexadiene; electron energy loss spectroscopy; germanium; surface chemical reaction; ultraviolet photoelectron spectroscopy;

D O I：

10.1016/S0039-6028(98)00410-5

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The adsorption and reaction of 1,3-cyclohexadiene with the Ge(100)-(2 x 1) surface are investigated. The possibility of a surface Diels-Alder reaction ([4+2] cycloaddition), as well as a [2+2] cycloaddition reaction are explored. The surface reactions are followed by ultraviolet photoelectron and high-resolution electron energy loss spectroscopies. The vibrational spectroscopy results are compared with theoretically predicted frequencies for each of the possible surface reactions. (C) 1998 Published by Elsevier Science B.V. All rights reserved.

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页码：L773 / L778

页数：6

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