Creep properties beyond 1100°C and microstructure of Co-Re-Cr alloys

被引:26
作者
Brunner, Martin [1 ]
Huettner, Rainer [1 ]
Boelitz, Marie-Christin [1 ]
Voelkl, Rainer [1 ]
Mukherji, Debashis [2 ]
Roesler, Joachim [2 ]
Depka, Timo [3 ]
Somsen, Christoph [3 ]
Eggeler, Gunther [3 ]
Glatzel, Uwe [1 ]
机构
[1] Univ Bayreuth, D-95440 Bayreuth, Germany
[2] Tech Univ Carolo Wilhelmina Braunschweig, Inst Werkstoffe, D-38106 Braunschweig, Germany
[3] Ruhr Univ Bochum, Inst Werkstoffe, D-44780 Bochum, Germany
来源
MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING | 2010年 / 528卷 / 02期
关键词
High temperature materials; Co-Re-Cr; Creep; Microstructure; TEM; HIGH-TEMPERATURE ALLOYS; MO-SI; OXIDATION RESISTANCE; BASE ALLOYS; STRENGTH; COBALT; 1000-DEGREES-C; SUPERALLOYS;
D O I
10.1016/j.msea.2010.09.035
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
The melting point of a novel Co-17Re-23Cr alloy (numbers given in at.%) could be increased by 250 C as compared to established Ni-based superalloys, by optimising the content of Re. Samples were produced by vacuum arc-melting in order to evaluate the creep behaviour at temperatures beyond 1100 degrees C and for microstructural analysis. Three alloys (the Co-17Re-23Cr-based material, and the carbide strengthened alloys Co-17Re-23Cr-2.6C and Co-17Re-23Cr-2.6C-1.2Ta) were investigated. Creep properties, especially the minimum creep rate and the Larson-Miller plots, were compared. The Co-17Re-23Cr-2.6C-1.2Ta alloy has a higher minimum creep rate than Co-17Re-23Cr at 1200 degrees C but it has a lower minimum creep rate than Co-17Re-23Cr at 1100 degrees C. TaC coarsening, detected via transmission electron microscope (TEM) measurements may explain this effect. The overall creep behaviour of Co-17Re-23Cr-2.6C at 1200 degrees C is better than that of Co-17Re-23Cr-2.6C-1.2Ta, but worse than that of Co-17Re-23Cr. Microstructural investigations by scanning electron microscopy and TEM reveal a hexagonal closed-packed (hcp) matrix and sigma-phases. The microhardness of the sigma-phase was about 1570 HV (load: 1 g) and around 800 HV for the matrix. Pores and cracks occur along the brittle sigma-phases and grain boundaries in the Co-Re-Cr alloys. A Norton exponent n in between 1.4 and 3.0 points to grain boundary dominated creep mechanisms. (C) 2010 Elsevier B.V. All rights reserved.
引用
收藏
页码:650 / 656
页数:7
相关论文
共 26 条
[1]  
Beltran A.M., 1987, Superalloys II, P135
[2]   COBALT-BASED SUPERALLOYS FOR APPLICATIONS IN GAS-TURBINES [J].
COUTSOURADIS, D ;
DAVIN, A ;
LAMBERIGTS, M .
MATERIALS SCIENCE AND ENGINEERING, 1987, 88 :11-19
[3]   Microstructures of Co-Re-Cr, Mo-Si and Mo-Si-B high-temperature alloys [J].
Depka, T. ;
Somsen, Ch. ;
Eggeler, G. ;
Mukherji, D. ;
Roesler, J. ;
Krueger, M. ;
Saage, H. ;
Heilmaier, M. .
MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING, 2009, 510-11 :337-341
[4]   Mo-Si-B alloys: Developing a revolutionary turbine-engine material [J].
Dimiduk, DM ;
Perepezko, JH .
MRS BULLETIN, 2003, 28 (09) :639-645
[5]  
Gabb T.P., 1987, Superalloys, VII, P575
[6]   Metallic materials for structural applications beyond nickel-based superalloys [J].
Heilmaier, M. ;
Krueger, M. ;
Saage, H. ;
Roesler, J. ;
Mukherji, D. ;
Glatzel, U. ;
Voelkl, R. ;
Huettner, R. ;
Eggeler, G. ;
Somsen, Ch. ;
Depka, T. ;
Christ, H. -J. ;
Gorr, B. ;
Burk, S. .
JOM, 2009, 61 (07) :61-67
[7]  
Hüttner R, 2008, SUPERALLOYS 2008, P719, DOI 10.7449/2008/Superalloys_2008_719_723
[8]   Oxidation behaviour of experimental Co-Re-base alloys in laboratory air at 1000°C [J].
Klauke, Michael ;
Mukherji, Debashis ;
Gorr, Bronislava ;
da Trindade Filho, Vicente Braz ;
Roesler, Joachim ;
Christ, Hans-Juergen .
INTERNATIONAL JOURNAL OF MATERIALS RESEARCH, 2009, 100 (01) :104-111
[9]  
Kolbe M, 1999, MATERIALWISS WERKST, V30, P465, DOI 10.1002/(SICI)1521-4052(199908)30:8<465::AID-MAWE465>3.3.CO
[10]  
2-C