Versatile direct dehydrative approach for diaryliodonium(III) salts in fluoroalcohol media

被引：108

作者：

Dohi, Toshifumi ^{[1
]}

Ito, Motoki ^{[1
]}

Morimoto, Koji ^{[1
]}

Minamitsuji, Yutaka ^{[1
]}

Takenaga, Naoko ^{[1
]}

Kita, Yasuyuki ^{[1
]}

机构：

[1] Osaka Univ, Grad Sch Pharmaceut Sci, Suita, Osaka 5650871, Japan

来源：

CHEMICAL COMMUNICATIONS | 2007年 / 40期

关键词：

D O I：

10.1039/b708802g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We have found that the use of fluoroalcohol media greatly enhanced the efficiency and scope of the direct dehydrative condensation of arenes 1 and hypervalent iodine( III) compounds; the present clean method has a broad range of applicability as well as unique selectivity in the aromatic substrates, and is highly efficient even in polymer functionalization.

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收藏

页码：4152 / 4154

页数：3

相关论文

共 31 条

[1] Fluorinated alcohols:: A new medium for selective and clean reaction [J].

Bégué, JP ;

Bonnet-Delpon, D ;

Crousse, B .

SYNLETT, 2004, (01) :18-29

[2] DIARYLIODONIUM SALTS .14. REACTIONS OF ORGANOMETALLIC COMPOUNDS WITH IODOSOBENZENE DICHLORIDES AND WITH IODONIUM SALTS [J].

BERINGER, FM ;

DEHN, JW ;

WINICOV, M .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1960, 82 (11) :2948-2952

[3] DIARYLIODONIUM SALTS .1. SYNTHESIS [J].

BERINGER, FM ;

DREXLER, M ;

GINDLER, EM ;

LUMPKIN, CC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1953, 75 (11) :2705-2708

[4] High-yielding one-pot synthesis of diaryliodonium triflates from arenes and iodine or aryl iodides [J].

Bielawski, Marcin ;

Olofsson, Berit .

CHEMICAL COMMUNICATIONS, 2007, (24) :2521-2523

[5] New synthesis of diaryliodonium sulfonates from arylboronic acids [J].

Carroll, MA ;

Pike, VW ;

Widdowson, DA .

TETRAHEDRON LETTERS, 2000, 41 (28) :5393-5396

[6]

CRIVELLO JV, 1986, POLYM BULL, V16, P243

[7] The synthesis of head-to-tail (H-T) dimers of 3-substituted thiophenes by the hypervalent iodine(III)-induced oxidative biaryl coupling reaction [J].

Dohi, T ;

Morimoto, K ;

Kiyono, Y ;

Maruyama, A ;

Tohma, H ;

Kita, Y .

CHEMICAL COMMUNICATIONS, 2005, (23) :2930-2932

[8] First hypervalent iodine(III)-catalyzed C-N bond forming reaction:: catalytic spirocyclization of amides to N-fused spirolactams [J].

Dohi, Toshifumi ;

Maruyama, Akinobu ;

Minamitsuji, Yutaka ;

Takenaga, Naoko ;

Kita, Yasuyuki .

CHEMICAL COMMUNICATIONS, 2007, (12) :1224-1226

[9] Making radical cations live longer [J].

Eberson, L ;

Hartshorn, MP ;

Persson, O ;

Radner, F .

CHEMICAL COMMUNICATIONS, 1996, (18) :2105-2112

[10] THE PHOTOGENERATION OF ACID AND BASE WITHIN POLYMER-COATINGS - APPROACHES TO POLYMER CURING AND IMAGING [J].

FRECHET, JMJ .

PURE AND APPLIED CHEMISTRY, 1992, 64 (09) :1239-1248

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