3,3′-Bis(quinolin-8-yl)-1,1′-[4,4′-methylenebis(4,1-phenylene)]diurea

被引:1
作者
Pramanik, Avijit [1 ]
Russ, Tiffany H. [1 ]
Powell, Douglas R. [2 ]
Hossain, Md. Alamgir [1 ]
机构
[1] Jackson State Univ, Dept Chem & Biochem, Jackson, MS 39217 USA
[2] Univ Oklahoma, Dept Chem & Biochem, Norman, OK 73019 USA
来源
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2012年 / 68卷
基金
美国国家科学基金会;
关键词
UREA;
D O I
10.1107/S1600536811053220
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The title compound, C(33)H(26)N(6)O(2), contains two 3-(quinolin-8-yl) urea groups linked to a diphenylmethane. The asymmetric unit contains two molecules, A and B. Each quinoline plane is essentially parallel to the attached urea unit [dihedral angles = 8.97 (18) and 8.81 (19) in molecule A and 18.47 (18) and 4.09 (19)degrees in molecule B]. The two benzene rings are twisted, making dihedral angles of 81.36 (8)degrees in A and 87.20 (9)degrees in B. The molecular structures are stabilized by intramolecular N-H center dot center dot center dot N hydrogen bonds. In the crystal, each urea O atom is involved in two N-H center dot center dot center dot O hydrogen bonds, generating two interpenetrating three-dimensional sets of molecules.
引用
收藏
页码:o158 / o159
页数:18
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