Samarium diiodide-mediated reaction of organic halides with carbonyl compounds

被引：10
|
作者：
Utimoto, K [1 ]
Matsubara, S [1 ]
机构：
[1] Kyoto Univ, Grad Sch Engn, Dept Chem Mat, Kyoto 6068501, Japan
来源：
JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN | 1998年 / 56卷 / 11期
关键词：
D O I：
10.5059/yukigoseikyokaishi.56.908
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The following three types of samarium diiodide mediated reactions of organic halides and carbonyl compounds are discussed: 1) Samarium-mediated highly stereoselective reaction of 1,1-dihaloalkanes with aldehydes. 2) Stereoselective reaction with configurationally stable alpha-phenylthioalkylsamarium compounds. 3) Preparation and reaction of a samarium enolate equivalent of beta-ketoester.
引用
收藏
页码：908 / 918
页数：11
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