Samarium diiodide-mediated reaction of organic halides with carbonyl compounds

被引：10

作者：

Utimoto, K ^{[1
]}

Matsubara, S ^{[1
]}

机构：

[1] Kyoto Univ, Grad Sch Engn, Dept Chem Mat, Kyoto 6068501, Japan

来源：

JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN | 1998年 / 56卷 / 11期

关键词：

D O I：

10.5059/yukigoseikyokaishi.56.908

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The following three types of samarium diiodide mediated reactions of organic halides and carbonyl compounds are discussed: 1) Samarium-mediated highly stereoselective reaction of 1,1-dihaloalkanes with aldehydes. 2) Stereoselective reaction with configurationally stable alpha-phenylthioalkylsamarium compounds. 3) Preparation and reaction of a samarium enolate equivalent of beta-ketoester.

引用

页码：908 / 918

页数：11

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