Efficient catalytic conversion of fructose into hydroxymethylfurfural by a novel carbon-based solid acid

被引：299

作者：

Wang, Jianjian ^{[1
]}

Xu, Wenjie ^{[1
]}

Ren, Jiawen ^{[1
]}

Liu, Xiaohui ^{[1
]}

Lu, Guanzhong ^{[1
]}

Wang, Yanqin ^{[1
]}

机构：

[1] E China Univ Sci & Technol, Key Lab Adv Mat, Res Inst Ind Catalysis, Shanghai 200237, Peoples R China

来源：

GREEN CHEMISTRY | 2011年 / 13卷 / 10期

基金：

中国国家自然科学基金;

关键词：

DEHYDRATION; GLUCOSE; HYDROLYSIS; CELLULOSE; WATER;

D O I：

10.1039/c1gc15306d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel carbon-based solid acid, which was prepared by a facile and eco-friendly approach from glucose and p-toluenesulfonic acid (TsOH), was used to catalyze fructose dehydration into 5-hydroxymethylfurfural (HMF) for the first time and exhibits excellent catalytic performance. As high as 91.2% yield of HMF was achieved in dimethyl sulfoxide (DMSO) at 130 degrees C after only 1.5 h. Besides, this catalyst also displayed a good reusability.

引用

页码：2678 / 2681

页数：4

共 27 条

[1] Acid-catalyzed production of 5-hydroxymethyl furfural from D-fructose in subcritical water [J].

Asghari, FS ;

Yoshida, H .

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2006, 45 (07) :2163-2173

[2] Dehydration of fructose to 5-hydroxymethylfurfural in sub- and supercritical acetone [J].

Bicker, M ;

Hirth, J ;

Vogel, H .

GREEN CHEMISTRY, 2003, 5 (02) :280-284

[3] Dehydration of D-fructose to hydroxymethylfurfural in sub- and supercritical fluids [J].

Bicker, M ;

Kaiser, D ;

Ott, L ;

Vogel, H .

JOURNAL OF SUPERCRITICAL FLUIDS, 2005, 36 (02) :118-126

[4] Heterogeneous catalysts based on vanadyl phosphate for fructose dehydration to 5-hydroxymethyl-2-furaldehyde [J].

Carlini, C ;

Patrono, P ;

Galletti, AMR ;

Sbrana, G .

APPLIED CATALYSIS A-GENERAL, 2004, 275 (1-2) :111-118

[5]

Carlini C., 2006, CATAL TODAY, V118, P373

[6] Liquid-phase catalytic processing of biomass-derived oxygenated hydrocarbons to fuels and chemicals [J].

Chheda, Juben N. ;

Huber, George W. ;

Dumesic, James A. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2007, 46 (38) :7164-7183

[7] Production of 5-hydroxymethylfurfural and furfural by dehydration of biomass-derived mono- and poly-saccharides [J].

Chheda, Juben N. ;

Roman-Leshkov, Yuriy ;

Dumesic, James A. .

GREEN CHEMISTRY, 2007, 9 (04) :342-350

[8] Synergy of boric acid and added salts in the catalytic dehydration of hexoses to 5-hydroxymethylfurfural in water [J].

Hansen, Thomas S. ;

Mielby, Jerrik ;

Riisager, Anders .

GREEN CHEMISTRY, 2011, 13 (01) :109-114

[9] A carbon material as a strong protonic acid [J].

Hara, M ;

Yoshida, T ;

Takagaki, A ;

Takata, T ;

Kondo, JN ;

Hayashi, S ;

Domen, K .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (22) :2955-2958

[10] Production of liquid alkanes by aqueous-phase processing of biomass-derived carbohydrates [J].

Huber, GW ;

Chheda, JN ;

Barrett, CJ ;

Dumesic, JA .

SCIENCE, 2005, 308 (5727) :1446-1450

← 1 2 3 →