Synthesis and characterization of a new benzofulvene polymer showing a thermoreversible polymerization behavior

被引:71
作者
Cappelli, A
Mohr, GL
Anzini, M
Vomero, S
Donati, A
Casolaro, M
Mendichi, R
Giorgi, G
Makovec, F
机构
[1] Univ Siena, Dipartimento Farmacochim Tecnol, I-53100 Siena, Italy
[2] Univ Siena, Dipartimento Sci Chim & Biosistemi, I-53100 Siena, Italy
[3] CNR, Ist Studio Macromol, I-20133 Milan, Italy
[4] Univ Siena, Ctr Interdipartimento Anal & Determinaz Struttura, I-53100 Siena, Italy
[5] Rotta Res Lab SpA, I-20052 Monza, Italy
关键词
D O I
10.1021/jo035104h
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A new polymer based on a functionalized benzofulvene moiety has been synthesized by spontaneous polymerization of the monomer in the solid state. This polymer shows a very high molar mass, high solubility in the most common organic solvents, and thermoreversible polymerization properties. An interesting application in synthesis is reported.
引用
收藏
页码:9473 / 9476
页数:4
相关论文
共 11 条
[1]   AN ORIGINAL AND UNEXPECTED SYNTHESIS OF FUNCTIONAL ISOCOUMARINS [J].
BABIN, P ;
DUNOGUES, J .
TETRAHEDRON LETTERS, 1984, 25 (39) :4389-4392
[2]   FULVENES AND SUBSTITUTED FULVENES [J].
BERGMANN, ED .
CHEMICAL REVIEWS, 1968, 68 (01) :41-&
[3]   9-Methyl-1-3,4-benzfluorene [J].
Fieser, LF ;
Joshel, LM .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1940, 62 :957-958
[4]   Bond forming initiation of ''charge-transfer'' polymerizations and the accompanying cycloadditions [J].
Hall, HK ;
Padias, AB .
ACCOUNTS OF CHEMICAL RESEARCH, 1997, 30 (08) :322-329
[5]   ELECTROPHILIC PROPERTIES OF ETHYL 3-PHENYLINDONE-2-CARBOXYLATE [J].
KOELSCH, CF .
JOURNAL OF ORGANIC CHEMISTRY, 1960, 25 (12) :2088-2091
[6]   Dibenzofulvene, a 1,1-diphenylethylene analogue, gives a π-stacked polymer by anionic, free-radical, and cationic catalysts [J].
Nakano, T ;
Takewaki, K ;
Yade, T ;
Okamoto, Y .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (37) :9182-9183
[7]   BAND STRUCTURES OF POLYFULVENE AND RELATED POLYMERS - A MODEL FOR THE EFFECTS OF BENZANNELATION ON THE BAND STRUCTURES OF POLYTHIOPHENE, POLYPYRROLE, AND POLYFULVENE [J].
PRANATA, J ;
GRUBBS, RH ;
DOUGHERTY, DA .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (11) :3430-3435
[8]   Self-assembly of conjugated polymers at the air/water interface. Structure and properties of Langmuir and Langmuir-Blodgett films of amphiphilic regioregular polythiophenes [J].
Reitzel, N ;
Greve, DR ;
Kjaer, K ;
Hows, PB ;
Jayaraman, M ;
Savoy, S ;
McCullough, RD ;
McDevitt, JT ;
Bjornholm, T .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (24) :5788-5800
[9]  
SUDA M, 1981, SYNTHESIS-STUTTGART, P714
[10]   UTILITY OF PHOSPHONATE CARBANIONS IN OLEFIN SYNTHESIS [J].
WADSWORTH, W ;
EMMONS, WD .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1961, 83 (07) :1733-&