Syntheses and structures of two new inorganic-organic hybrid nickel vanadates [Ni(H2biim)3]V2O6 and [Ni(H2biim)3][(VO2)(SO4)] (H2biim=2,2′-biimidazole)

被引：0

作者：

Miao, Fangfang ^{[1
,2
,3
]}

Zhang, Mimei ^{[2
]}

Zhou, Yinzhuang ^{[1
,3
]}

机构：

[1] Beijing Univ Agr, Coll Biosci & Resources Environm, Minist Agr & Rural Affairs, Key Lab Northern Urban Agr, Beijing 102206, Peoples R China

[2] North China Elect Power Univ, Coll Environm Sci & Engn, MOE Key Lab Resources & Environm Syst Optimizat, Beijing 102206, Peoples R China

[3] Capital Normal Univ, Dept Chem, Beijing 100048, Peoples R China

来源：

JOURNAL OF MOLECULAR STRUCTURE | 2022年 / 1247卷

关键词：

Nickle bimetallic complexes; Bi-imidazole ligand; Hydrothermal synthesis; Inorganic-organic hybrid materials; Vanadium oxide-sulfur chain; MOLYBDENUM-VANADIUM POLYOXOMETALATE; CRYSTAL-STRUCTURES; SCHIFF-BASE; COMPLEXES; CLUSTER;

D O I：

10.1016/j.molstruc.2021.131286

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Two novel inorganic-organic hybrid vanadates complexes [Ni(H(2)biim)(3)]V2O6 (H(2)biim = 2,2'-biimidazole) 1 and [Ni(H(2)biim)(3)][(VO2)(SO4)](2) have been synthesized under hydrothermal synthesis and characterized by single-crystal X-ray diffraction. Compound 1 consists of (VO3)-n unit and compound 2 consists of (VO-S)(n) one dimensional chains and in compound 2 the anion SO42- was linked to the vanadium atom via the oxygen atom. IR, thermogravimetric analysis and fluorescence detection were also described in this paper and Compound 2 showed fluorescence properties. (C) 2021 Elsevier B.V. All rights reserved.

引用

页数：7

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