NHPI/tert-butyl nitrite: A highly efficient metal-free catalytic system for aerobic oxidation of alcohols to carbonyl compounds using molecular oxygen as the terminal oxidant

被引：35

作者：

Hu, Yongke ^{[1
]}

Chen, Lei ^{[1
]}

Li, Bindong ^{[1
]}

机构：

[1] Nanjing Univ Sci & Technol, Sch Chem Engn, Nanjing 210094, Jiangsu, Peoples R China

来源：

CATALYSIS COMMUNICATIONS | 2016年 / 83卷

关键词：

Aerobic oxidation; Alcohol; tert-Butyl nitrite (TBN); N-Hydroxyphthalimide (NHPI); N-HYDROXYPHTHALIMIDE; SECONDARY ALCOHOLS; ACID; FUNCTIONALIZATION; ACTIVATION; NITRATION; DIOXIDE;

D O I：

10.1016/j.catcom.2016.05.017

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A highly practical metal-free catalytic system has been developed for aerobic oxidation of alcohols to corresponding ketones and aldehydes using catalytic amount of N-hydroxyphthalimide (NHPI) and tert-butyl nitrite (TBN) with molecular oxygen serving as the terminal oxidant. A variety of aliphatic, aromatic, allylic, and heterocyclic alcohols were smoothly converted to desired products with moderate to excellent yields. Moreover, a possible radical mechanism was proposed. (C) 2016 Elsevier B.V. All rights reserved.

引用

页码：82 / 87

页数：6

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