On-line solid-phase extraction and HPLC determination of polycyclic aromatic hydrocarbons in water using fluorocarbon polymer sorbents

被引：87

作者：

Oliferova, L ^{[1
]}

Statkus, M ^{[1
]}

Tsysin, G ^{[1
]}

Shpigun, O ^{[1
]}

Zolotov, Y ^{[1
]}

机构：

[1] Moscow MV Lomonosov State Univ, Dept Chem, Div Analyt Chem, Moscow 119992, Russia

来源：

ANALYTICA CHIMICA ACTA | 2005年 / 538卷 / 1-2期

基金：

俄罗斯基础研究基金会;

关键词：

on-line; SPE; HPLC; PAH; fluorocarbon polymers; sorption;

D O I：

10.1016/j.aca.2005.01.061

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

Polyvinylidenefluoride (fluorocarbon polymer sorbent) with surface area 8.4 m(2) g(-1) and particle size 15-30 mu m was used for on-line SPE-HPLC determination of naphthalene, biphenyl, acenaphthene, anthracene and pyrene in natural water. Desorption eluent flow rates were varied from 0.50 to 1.75 ml min(-1) and the volume of analyte-containing eluent stream zone was 0.10-0.11 ml, while empty preconcentration column volume is 0.10 ml. Detection limits of SPE-HPLC method were established: 5 ng 1(-1) (biphenyl), 7 ng 1(-1) (anthracene), 8 ng 1(-1) (acenaphthene), 30 ng 1(-1) (pyrene), 40 ng 1(-1) (naphthalene), using UV spectrophotometric detection. Several samples of natural and potable water were spiked with mixture of PAHs, thus validating the proposed technique. (c) 2005 Elsevier B.V. All rights reserved.

引用

页码：35 / 40

页数：6

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