Assembly of hydrogen bonded diamondoid networks based on synthetic metal-organic tetrahedral nodes

被引：53

作者：

Ma, BQ ^{[1
]}

Sun, HL

Gao, S

机构：

[1] Peking Univ, State Key Lab Rare Earth Mat Chem & Applicat, Beijing 100871, Peoples R China

[2] Peking Univ, PKU HKU Joint Lab Rare Earth Mat & Bioinorgan Che, Coll Chem & Mol Engn, Beijing 100871, Peoples R China

来源：

INORGANIC CHEMISTRY | 2005年 / 44卷 / 04期

关键词：

D O I：

10.1021/ic048648q

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction of Mn(ClO4)(2) or Co(PF6)(2) with 4,4'-dipyridine-dioxide (dpdo) produced novel molecular species [M(dpdo)(4)(H2O)(2)](2+), which hold a tetrahedral configuration notwithstanding their octahedral environment around the metal centers. The tetrahedral moieties are further assembled through hydrogen bonds between peripheral NO ends of dpdo ligands and coordinated water molecules, giving rise to 3D diamondoid networks.

引用

页码：837 / 839

页数：3

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