Flue-gas carbon capture on carbonaceous sorbents: Toward a low-cost multifunctional Carbon Filter for "Green" energy producers

被引:189
作者
Radosz, Maciej [1 ]
Hu, Xudong [1 ]
Krutkramelis, Kaspars [1 ]
Shen, Youqing [1 ]
机构
[1] Univ Wyoming, Dept Chem & Petr Engn, Soft Mat Lab, Laramie, WY 82071 USA
关键词
D O I
10.1021/ie0707974
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
A low-pressure Carbon Filter Process (patent pending) is proposed to capture carbon dioxide (CO2) from flue gas. This filter is filled with a low-cost carbonaceous sorbent, such as activated carbon or charcoal, which has a high affinity (and, hence, high capacity) to CO2 but not to nitrogen (N-2). This, in turn, leads to a high CO2/N-2 selectivity, especially at low pressures. The Carbon Filter Process proposed in this work can recover at least 90% of flue-gas CO2 of 90%+ purity at a fraction of the cost normally associated with the conventional amine absorption process. The Carbon Filter Process requires neither expensive materials nor flue-gas compression or refrigeration, and it is easy to heat integrate with an existing or grassroots power plant without affecting the cost of the produced electricity too much. An abundant supply Of low-cost CO2 from electricity producers is good news for enhanced oil recovery (EOR) and enhanced coal-bed methane recovery (ECBMR) operators, because it will lead to higher oil and gas recovery rates in an environmentally sensitive manner. A CO2-rich mixture that contains some nitrogen is much less expensive to separate from flue-gas than pure CO2; therefore, mixed CO2/N-2-EOR and CO2/N-2-ECBMR methods are proposed to maximize the overall carbon capture and utilization efficiency.
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收藏
页码:3783 / 3794
页数:12
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