A Mild, Highly Efficient Addition of Alkynes to Aldehydes Catalyzed by Titanium Dioxide-Supported Silver Nanoparticles

被引：22

作者：

Yu, Min ^{[1
]}

Wang, Yong ^{[1
]}

Sun, Weijiang ^{[1
]}

Yao, Xiaoquan ^{[1
]}

机构：

[1] Nanjing Univ Aeronaut & Astronaut, Dept Appl Chem, Sch Mat Sci & Engn, Nanjing 210016, Peoples R China

来源：

ADVANCED SYNTHESIS & CATALYSIS | 2012年 / 354卷 / 01期

基金：

中国国家自然科学基金;

关键词：

ligand promotion; propargylic alcohols; silver nanoparticles; support effects; DEFICIENT PROPARGYLIC ALCOHOLS; 1,3-DIPOLAR CYCLOADDITION; COPPER NANOPARTICLES; GOLD NANOPARTICLES; CU-NANOPARTICLES; GREEN SYNTHESIS; ISOMERIZATION; ACTIVATION; ALKYNYLATION; AMINES;

D O I：

10.1002/adsc.201100518

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Titanium dioxide-supported silver nanoparticles were utilized as a highly efficient catalyst for the addition of terminal alkynes to aldehydes to prepare propargylic alcohols with the promotion by triphenylphosphine. Both a significant support effect and a ligand effect were observed in the catalytic reaction. With this protocol, various propargylic alcohol derivatives were synthesized from aldehydes and terminal alkynes in good to excellent yields. Furthermore, the catalyst could be recovered and reused effectively without obvious reduction in catalytic activity.

引用

页码：71 / 76

页数：6

共 26 条

[21] Highly efficient three-component coupling reaction catalyzed by gold nanoparticles supported on periodic mesoporous organosilica with ionic liquid framework
Karimi, Babak
Gholinejad, Mohammad
Khorasani, Mojtaba
CHEMICAL COMMUNICATIONS, 2012, 48 (71) : 8961 - 8963
[22] Pt, Pd and Au nanoparticles supported on a DNA-MMT hybrid: efficient catalysts for highly selective oxidation of primary alcohols to aldehydes, acids and esters
Tang, Lin
Guo, Xuefeng
Li, Yunfeng
Zhang, Shuai
Zha, Zhenggen
Wang, Zhiyong
CHEMICAL COMMUNICATIONS, 2013, 49 (45) : 5213 - 5215
[23] Highly Efficient Aqueous Synthesis of Propargylamines through C-H Activation Catalyzed by Magnetic Organosilica-Supported Gold Nanoparticles as an Artificial Metalloenzyme
Aghahosseini, Hamideh
Rezaei, Seyed Jamal Tabatabaei
Tadayyon, Mahsa
Ramazani, Ali
Amani, Vahid
Ahmadi, Roya
Abdolahnjadian, Davod
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2018, (22) : 2589 - 2598
[24] Investigation into the highly efficient Artemisia absinthium-silver nanoparticles composite as a novel environmentally benign corrosion inhibitor for mild steel in 1M HCl
Mobin, Mohammad
Ahmad, Irfan
Shoeb, Mohd
JOURNAL OF ADHESION SCIENCE AND TECHNOLOGY, 2022, 36 (23-24) : 2562 - 2587
[25] Synthesis of Ultrafine Silver Nanoparticles on the Surface of Fe3O4@SiO2@KIT-6-NH2 Nanocomposite and Their Application as a Highly Efficient and Reusable Catalyst for Reduction of Nitrofurazone and Aromatic Nitro Compounds Under Mild Conditions
Ansari, Sara
Khorshidi, Alireza
Shariati, Shahab
CATALYSIS LETTERS, 2019, 149 (02) : 410 - 418
[26] Synthesis of Ultrafine Silver Nanoparticles on the Surface of Fe3O4@SiO2@KIT-6-NH2 Nanocomposite and Their Application as a Highly Efficient and Reusable Catalyst for Reduction of Nitrofurazone and Aromatic Nitro Compounds Under Mild Conditions
Sara Ansari
Alireza Khorshidi
Shahab Shariati
Catalysis Letters, 2019, 149 : 410 - 418

← 1 2 3 →