Electrical characterization of amorphous silicon carbide thin films deposited via polymeric source chemical vapor deposition

被引:12
作者
Fanaei, T.
Camjre, N. [1 ]
Aktik, C.
Gujrathi, S. [2 ]
Lessard, A. [1 ]
Awad, Y. [1 ]
Oulachgar, E.
Scarlete, M. [3 ]
机构
[1] SiXtron Adv Mat Inc, Sherbrooke, PQ J1J 2E8, Canada
[2] Univ Montreal, Dept Phys, Grp Rech Phys & Technol Couches Minces, Montreal, PQ H3C 3J7, Canada
[3] Bishops Univ, Dept Chem, Lennoxville, PQ J1M 1Z7, Canada
关键词
amorphous silicon carbide (a-SiC); polymer-source chemical vapor deposition (PS-CVD); CV measurements; Fourier transform infrared spectroscopy (FTIR); deposition temperature;
D O I
10.1016/j.tsf.2007.06.072
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Polymeric source chemical vapor deposition (PS-CVD) was used to synthesize amorphous silicon carbide (a-SiC) thin films. The PS-CVD process was conducted at temperatures between 750 and 1000 degrees C. The substrates used were silicon single crystal wafers of p-type and n-type, and thermally grown silicon dioxide substrates. The chemical and electrical properties of the films were studied by various techniques, including Fourier transform infrared spectroscopy, elastic recoil detection (ERD), and capacitance-voltage technique. A correlation was observed between the average concentration of oxygen in the films and the deposition temperature, linking a low oxygen concentration to a high deposition temperature. However, the concentration of oxygen in the films deposited at the same temperature is independent of the substrate. The thin films deposited at low temperature showed insulating behaviour, while the semiconducting behaviour is obtained at high deposition temperatures. Ohmic contacts were obtained on the deposited semiconductor thin film by evaporating nickel contacts, followed by annealing of the sample at 800 degrees C for 2 min. (c) 2007 Elsevier B.V. All rights reserved.
引用
收藏
页码:3755 / 3760
页数:6
相关论文
共 27 条
[1]   Plasma assisted process for deposition of silicon carbide thin films [J].
Cho, NI ;
Choi, Y ;
Noh, SJ .
CURRENT APPLIED PHYSICS, 2006, 6 (02) :161-165
[2]  
CHO NJ, 2002, ADV TECH MAT MAT P J, V4, P96
[3]   PHYSICAL-PROPERTIES OF UNDOPED AND DOPED HYDROGENATED AMORPHOUS-SILICON CARBIDE [J].
DEMICHELIS, F ;
PIRRI, CF ;
TRESSO, E ;
DELLAMEA, G ;
RIGATO, V ;
RAVA, P .
SEMICONDUCTOR SCIENCE AND TECHNOLOGY, 1991, 6 (12) :1141-1146
[4]   Chemical synthesis of microporous nonoxide ceramics from polysilazanes [J].
Dismukes, JP ;
Johnson, JW ;
Bradley, JS ;
Millar, JM .
CHEMISTRY OF MATERIALS, 1997, 9 (03) :699-706
[5]   Influence of crystal quality on the electronic properties of n-type 3C-SiC grown by low temperature low pressure chemical vapor deposition [J].
Eickhoff, M ;
Möller, H ;
Stoemenos, J ;
Zappe, S ;
Kroetz, G ;
Stutzmann, M .
JOURNAL OF APPLIED PHYSICS, 2004, 95 (12) :7908-7917
[6]   PHYSICAL-PROPERTIES OF THE X-RAY MEMBRANE MATERIALS [J].
ELKHAKANI, MA ;
CHAKER, M .
JOURNAL OF VACUUM SCIENCE & TECHNOLOGY B, 1993, 11 (06) :2930-2937
[7]   Stable ultraviolet photoluminescence from sol-gel silica containing nano-sized SiC/C powder [J].
Fu, ZP ;
Ning, JQ ;
Yang, BF ;
Wu, W ;
Pan, HB ;
Xu, PS .
MATERIALS LETTERS, 2003, 57 (13-14) :1910-1914
[8]   Microstructural interpretation of Ni ohmic contact on n-type 4H-SiC [J].
Han, SY ;
Shin, JY ;
Lee, BT ;
Lee, JL .
JOURNAL OF VACUUM SCIENCE & TECHNOLOGY B, 2002, 20 (04) :1496-1500
[9]   Mechanism of ohmic behavior of Al/Ti contacts to p-type 4H-SiC after annealing [J].
Johnson, BJ ;
Capano, MA .
JOURNAL OF APPLIED PHYSICS, 2004, 95 (10) :5616-5620
[10]   FTIR analysis of a-SiC:H films grown by plasma enhanced CVD [J].
Kaneko, Tsutomu ;
Nemoto, Dai ;
Horiguchi, Atsushi ;
Miyakawa, Nobuaki .
JOURNAL OF CRYSTAL GROWTH, 2005, 275 (1-2) :E1097-E1101