One-pot oxidative carbon-carbon bond formation of 3-benzylic and 3-allylic indoles with carbon nucleophiles

被引：14

作者：

Matsuo, Jun-ichi ^{[1
]}

Tanaki, Yumi ^{[1
]}

Ishibashi, Hiroyuki ^{[1
]}

机构：

[1] Kanazawa Univ, Grad Sch Nat Sci & Technol, Div Pharmaceut Sci, Kanazawa, Ishikawa 9201192, Japan

来源：

TETRAHEDRON | 2008年 / 64卷 / 22期

关键词：

D O I：

10.1016/j.tet.2008.03.033

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Indolenines were generated at -78 degrees C from 3-benzylic or 3-allylic indoles by dehydrogenation with N-tert-butylbenzenesulfinimidoyl chloride, and a carbon-carbon bond was formed at -78 degrees C in a one-pot manner by treating these indolenines with various carbon nucleophiles such as active methylene compounds or organocuprates. (c) 2008 Elsevier Ltd. All rights reserved.

引用

页码：5262 / 5267

页数：6

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