One-pot oxidative carbon-carbon bond formation of 3-benzylic and 3-allylic indoles with carbon nucleophiles

被引：14
|
作者：
Matsuo, Jun-ichi [1 ]
Tanaki, Yumi [1 ]
Ishibashi, Hiroyuki [1 ]
机构：
[1] Kanazawa Univ, Grad Sch Nat Sci & Technol, Div Pharmaceut Sci, Kanazawa, Ishikawa 9201192, Japan
来源：
TETRAHEDRON | 2008年 / 64卷 / 22期
关键词：
D O I：
10.1016/j.tet.2008.03.033
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Indolenines were generated at -78 degrees C from 3-benzylic or 3-allylic indoles by dehydrogenation with N-tert-butylbenzenesulfinimidoyl chloride, and a carbon-carbon bond was formed at -78 degrees C in a one-pot manner by treating these indolenines with various carbon nucleophiles such as active methylene compounds or organocuprates. (c) 2008 Elsevier Ltd. All rights reserved.
引用
收藏
页码：5262 / 5267
页数：6
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