Nickel-catalysed P-C bond formation via P-H/C-CN cross coupling reactions

被引:88
作者
Zhang, Ji-Shu [1 ]
Chen, Tieqiao [1 ]
Yang, Jia [1 ]
Han, Li-Biao [1 ,2 ]
机构
[1] Hunan Univ, State Key Lab Chemo Biosensing & Chemometr, Coll Chem & Chem Engn, Changsha 410082, Hunan, Peoples R China
[2] Natl Inst Adv Ind Sci & Technol, Tsukuba, Ibaraki 3058565, Japan
关键词
CARBON-CYANO; INTRAMOLECULAR ARYLCYANATION; PHOSPHINE OXIDES; ARYL HALIDES; H ARYLATION; PHOSPHORUS; CONSTRUCTION; DIPHENYLPHOSPHINE; CARBOCYANATION; PHOSPHONATION;
D O I
10.1039/c5cc01182e
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Nickel-catalysed P-H/C-CN cross coupling reactions take place efficiently under mild reaction conditions affording the corresponding sp(2)C-P bonds. This transformation provides a convenient method for the preparation of arylphosphines and arylphosphine oxides from the readily available P-H compounds and arylnitriles.
引用
收藏
页码:7540 / 7542
页数:3
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