Deoxygenation of amine N-oxides using gold nanoparticles supported on carbon nanotubes

被引：29

作者：

Donck, Simon ^{[1
,2
]}

Gravel, Edmond ^{[2
]}

Shah, Nimesh ^{[1
]}

Jawale, Dhanaji V. ^{[2
]}

Doris, Eric ^{[2
]}

Namboothiri, Irishi N. N. ^{[1
]}

机构：

[1] IIT, Dept Chem, Bombay 400076, Maharashtra, India

[2] CEA, Serv Chim Bioorgan & Marquage, iBiTecS, F-91191 Gif Sur Yvette, France

来源：

RSC ADVANCES | 2015年 / 5卷 / 63期

关键词：

EFFICIENT DEOXYGENATION; CATALYTIC-OXIDATION; PYRIDINE; NITROARENES; CONVERSION; SULFOXIDES; REDUCTION; WATER;

D O I：

10.1039/c5ra08845c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Deoxygenation of a variety of aromatic and aliphatic amine N-oxides has been carried out in excellent yield using dimethylphenylsilane as the reducing agent under the catalytic influence of a carbon nanotube-gold nanohybrid at room temperature. Low catalyst loading, good TON and TOF values, and recyclability of the catalyst are some of the salient features of our methodology.

引用

页码：50865 / 50868

页数：4

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