Regiocontrolled addition of carbonyl compounds with allylic indium generated by hydroindation of 1,3-dienes

被引：5
|
作者：
Hayashi, Naoki [1 ]
Honda, Hiroyuki [1 ]
Shibata, Ikuya [1 ]
Yasuda, Makoto [1 ]
Baba, Akio [1 ]
机构：
[1] Osaka Univ, Grad Sch Engn, Dept Appl Chem, Res Ctr Environm Preservat, Suita, Osaka 5650871, Japan
来源：
SYNLETT | 2008年 / 09期
关键词：
allylation; hydrides; indium; ketones; regioselectivity;
D O I：
10.1055/s-2008-1072753
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Allylic indiums, generated by a conjugate hydroindation of 1,3-dienes by HInCl(2), reacted with carbonyl compounds in a one-pot treatment. Both gamma- and alpha-adducts can be obtained depending upon the conditions used.
引用
收藏
页码：1407 / 1411
页数：5
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