Effect of C/S Ratio on Morphology and Structure of Hydrothermally Synthesized Calcium Silicate Hydrate

被引:62
作者
He Yongjia [1 ,2 ]
Zhao Xiaogang [1 ]
Lu Linnu [2 ,3 ]
Struble, Leslie J. [2 ]
Hu Shuguang [1 ]
机构
[1] Wuhan Univ Technol, Key Lab Silicate Mat Sci & Engn, Wuhan 430070, Peoples R China
[2] Univ Illinois, Dept Civil & Environm Engn, Urbana, IL 61801 USA
[3] Wuhan Univ Technol, Sch Sci, Wuhan 430070, Peoples R China
基金
中国国家自然科学基金;
关键词
calcium silicate hydrate; C/S ratio; morphology; structure; hydrothermal synthesis; C-S-H; GEL;
D O I
10.1007/s11595-011-0308-z
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The samples of the C-S-H series were synthesized by hydrothermal reaction of fumed silica, CaO and deionized water at initial C/S ratios between 1.0-1.7. Phase composition and structural and morphology characteristics of C-S-H samples were analyzed by XRD, IR and SEM. The experimental results showed that the d-spacing of (002), (110) and (020) decreased, the d-spacing of (200) increased, and the d-spacing of (310) varied randomly, the polymerization of silica tetrahedra of C-S-H decreased, and morphology of C-S-H samples varied from sheet shapes to long reticular fibers as C/S ratio increased.
引用
收藏
页码:770 / 773
页数:4
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