Hydrothermal synthesis and magnetic behaviour of beta-Li3VF6 and Na3VF6

被引：12

作者：

Ge, Lei ^{[1
]}

Yuan, Long ^{[1
]}

Huang, Keke ^{[1
]}

Feng, Wenchun ^{[2
]}

Fang, Hairui ^{[1
]}

Feng, Shouhua ^{[1
]}

机构：

[1] Jilin Univ, Coll Chem, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130012, Peoples R China

[2] Univ Michigan, Dept Chem Engn, Ann Arbor, MI 48109 USA

来源：

NEW JOURNAL OF CHEMISTRY | 2015年 / 39卷 / 07期

基金：

中国国家自然科学基金;

关键词：

COMPLEX FLUORIDES; LUMINESCENCE PROPERTIES; CRYSTAL-STRUCTURE; MILD CONDITIONS; CATALYSIS; CELLS; GEL; NANOCRYSTALS; LIBAF3; KMGF3;

D O I：

10.1039/c5nj00284b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Fluorides and oxide-fluorides play important roles in several technological fields. Herein, we have synthesized the crystals of beta-Li3VF6 and Na3VF6 under mild hydrothermal conditions without any hydrofluoric acid. These two compounds were well-crystallized and showed anti-ferromagnetic interactions with isolated magnetic units.

引用

页码：5080 / 5083

页数：4

共 44 条

[1] The Ag2O-V2O5-HF(aq) system and crystal structure of α-Ag3VO4 [J].

Albrecht, Thomas A. ;

Stern, Charlotte L. ;

Poeppelmeier, Kenneth R. .

INORGANIC CHEMISTRY, 2007, 46 (05) :1704-1708

[2]

Alter V. E., 1975, Z ANORG ALLG CHEM, V421, P110

[3] Facile synthesis of β-Li3VF6: A new electrochemically active lithium insertion material [J].

Basa, Anna ;

Gonzalo, Elena ;

Kuhn, Alois ;

Garcia-Alvarado, Flaviano .

JOURNAL OF POWER SOURCES, 2012, 207 :160-165

[4] Production of Al-Ti-B grain refining master alloys from B2O3 and K2TiF6 [J].

Birol, Yuecel .

JOURNAL OF ALLOYS AND COMPOUNDS, 2007, 443 (1-2) :94-98

[5] Enantioselective Acylation of Silyl Ketene Acetals through Fluoride Anion-Binding Catalysis [J].

Birrell, James A. ;

Desrosiers, Jean-Nicolas ;

Jacobsen, Eric N. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (35) :13872-13875

[6] The crystal structure of the weberite Na2MgInF7 [J].

Caramanian, A ;

Souron, JP ;

Gredin, P ;

de Kozak, A .

JOURNAL OF SOLID STATE CHEMISTRY, 2001, 159 (01) :234-238

[7] New Dion-Jacobson-type layered perovskite oxyfluorides, ASrNb2O6F (A = Li, Na, and Rb) [J].

Choy, JH ;

Kim, JY ;

Kim, SJ ;

Sohn, JS ;

Han, OH .

CHEMISTRY OF MATERIALS, 2001, 13 (03) :906-912

[8] EFFECT OF LONG-TERM ADMINISTRATION OF SODIUM-FLUORIDE ON PLASMA CALCIUM LEVEL IN RELATION TO INTESTINAL-ABSORPTION AND URINARY-EXCRETION IN RABBITS [J].

DAS, TK ;

SUSHEELA, AK .

ENVIRONMENTAL RESEARCH, 1993, 62 (01) :14-18

[9]

Duckworth RM, 2013, MONOGR ORAL SCI, V23, P125, DOI 10.1159/000350590

[10]

FARLEY JR, 1983, SCIENCE, V222, P330

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