Manganese Oxide-catalyzed Additive- and Solvent-free Aerobic Oxidative Synthesis of Primary Amides from Primary Amines

被引：14

作者：

Yamaguchi, Kazuya ^{[1
]}

Wang, Ye ^{[1
]}

Mizuno, Noritaka ^{[1
]}

机构：

[1] Univ Tokyo, Sch Engn, Dept Appl Chem, Bunkyo Ku, Tokyo 1138656, Japan

来源：

CHEMISTRY LETTERS | 2012年 / 41卷 / 06期

关键词：

OCTAHEDRAL MOLECULAR-SIEVES; HYDROXIDE CATALYST; EFFICIENT; HYDRATION; ALDOXIMES; NITRILES; ALCOHOLS; CONVERSION; ALDEHYDES; WATER;

D O I：

10.1246/cl.2012.633

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Various kinds of primary amides could be synthesized through indirect aerobic oxygenation of primary amines using simple amorphous MnO2 under additive- and solvent-free conditions. The catalyst/product separation was very easy, and the retrieved MnO2 catalyst could be reused without an appreciable loss of its high catalytic performance.

引用

页码：633 / 635

页数：3

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