Molecular and Macromolecular Engineering with Viologens as Building Blocks: Rational Design of Phosphorus-Viologen Dendritic Structures

被引:32
作者
Katir, Nadia [1 ,2 ]
Pierre Majoral, Jean [1 ,2 ]
El Kadib, Abdelkrim [1 ]
Caminade, Anne-Marie [2 ]
Bousmina, Mostapha [1 ]
机构
[1] ENSET, MAScIR Moroccan Fdn Adv Sci Innovat & Research, INANOTECH Inst Nanomat & Nanotechnol, Rabat 10100, Morocco
[2] CNRS, Lab Chim Coordinat, F-31077 Toulouse 4, France
关键词
Viologens; Dendrimers; Dendrons; Phosphorus; Synthesis design; GLASS SLIDES; DENDRIMERS; DNA; FUNCTIONALIZATION; NANOTUBES; COMPLEXES; CORE;
D O I
10.1002/ejoc.201101376
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The design of symmetric or asymmetric diversely functionalized monomer, dimer, or trimer viologens and the design of phosphorus building blocks allows the synthesis of unique types of mix phosphorus-viologen dendrimers. Strategies for the preparation of dendrimers of generations 0 and 1 are presented as are those for various dendrons. These methods exhibit broad applicability, high efficiency and usability, and are compatible with the presence of various functional groups (aldehyde, cyano, phenol, phosphonate, brominated groups).
引用
收藏
页码:269 / 273
页数:5
相关论文
共 59 条
[1]   "Viologen" Dendrimers as Antiviral Agents: The Effect of Charge Number and Distance [J].
Asaftei, Simona ;
De Clercq, Erik .
JOURNAL OF MEDICINAL CHEMISTRY, 2010, 53 (09) :3480-3488
[2]   Dendrimers Designed for Functions: From Physical, Photophysical, and Supramolecular Properties to Applications in Sensing, Catalysis, Molecular Electronics, Photonics, and Nanomedicine [J].
Astruc, Didier ;
Boisselier, Elodie ;
Ornelas, Catia .
CHEMICAL REVIEWS, 2010, 110 (04) :1857-1959
[3]   Host-guest complexes between an aromatic molecular tweezer and symmetric and unsymmetric dendrimers with a 4,4′-bipyridinium core [J].
Balzani, V ;
Bandmann, H ;
Ceroni, P ;
Giansante, C ;
Hahn, U ;
Klämer, FG ;
Müller, U ;
Müller, WM ;
Verhaelen, C ;
Vicinelli, V ;
Vögtle, F .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (02) :637-648
[4]   Ruthenium hydride and dihydrogen complexes with dendrimeric multidentate ligands [J].
Bardaji, M ;
Caminade, AM ;
Majoral, JP ;
Chaudret, B .
ORGANOMETALLICS, 1997, 16 (15) :3489-3497
[5]   Preparation, characterization, and electrochemical properties of a new series of hybrid dendrimers containing a viologen core and frechet and newkome dendrons [J].
Bhattacharya, Papri ;
Kaifer, Angel E. .
JOURNAL OF ORGANIC CHEMISTRY, 2008, 73 (15) :5693-5698
[6]   Hierarchically porous nanostructures through phosphonate-metal alkoxide condensation and growth using functionalized dendrimeric building blocks [J].
Brahmi, Younes ;
Katir, Nadia ;
Hameau, Aurelien ;
Essoumhi, Abdellatif ;
Essassi, El Mokhtar ;
Caminade, Anne-Marie ;
Bousmina, Mosto ;
Majoral, Jean-Pierre ;
El Kadib, Abdelkrim .
CHEMICAL COMMUNICATIONS, 2011, 47 (30) :8626-8628
[7]   First divergent strategy using two AB2 unprotected monomers for the rapid synthesis of dendrimers [J].
Brauge, L ;
Magro, G ;
Caminade, AM ;
Majoral, JP .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (27) :6698-6699
[8]   Functional dendritic polymer architectures as stimuli-responsive nanocarriers [J].
Calderon, Marcelo ;
Quadir, Mohiuddin A. ;
Strumia, Miriam ;
Haag, Rainer .
BIOCHIMIE, 2010, 92 (09) :1242-1251
[9]   Phosphorus dendrimers for the controlled elaboration of organic-inorganic materials [J].
Caminade, AM ;
Majoral, JP .
JOURNAL OF MATERIALS CHEMISTRY, 2005, 15 (35-36) :3643-3649
[10]   Dendrimers and DNA: Combinations of two special topologies for nanomaterials and biology [J].
Caminade, Anne-Marie ;
Turrin, Cedric-Olivier ;
Majoral, Jean-Pierre .
CHEMISTRY-A EUROPEAN JOURNAL, 2008, 14 (25) :7422-7432