Electrodeposited MoS2 counter electrode for flexible dye sensitized solar cell module with ionic liquid assisted photoelectrode

被引:42
|
作者
Gurulakshmi, M. [1 ]
Meenakshamma, A. [1 ]
Siddeswaramma, G. [1 ]
Susmitha, K. [1 ]
Subbaiah, Y. P. Venkata [1 ]
Narayana, T. [1 ]
Raghavender, M. [1 ]
机构
[1] Yogi Vemana Univ, Dept Phys, Kadapa 516005, India
关键词
Flexible DSSC; MoS2 counter electrode; Imidazolium iodide; Surface modification of PE; Semi-transparent flexible DSSC module; MOLYBDENUM-DISULFIDE; COMPOSITE FILMS; EFFICIENCY; PERFORMANCE; FABRICATION; OXIDE; COST; WS2;
D O I
10.1016/j.solener.2020.02.047
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
Dye-sensitized solar cell (DSSC) offers great advantages includes low cost materials, economic fabrication, suitable for low-light conversion, flexibility option, color design possibilities, etc. In the present study, a semitransparent, molybdenum disulphide (MoS2) flexible counter electrode (CE) is realized through electrodeposition method. Low temperature processed TiO2 solution is used for photoelectrode (PE) preparation. Conductive ionic liquid (BVImI + LiI) is used to modify the surface of photoelectrode for alteration of conduction band level of PE, towards enriched electron injection rate into TiO2. Flexible dye-sensitized solar cell (f-DSSC) fabricated by sandwich the photoelectrode and counter electrodes, and an ionic liquid electrolyte is injected. The surface modified photoelectrode (SM-PE) assisted test cell (0.16 cm(2) active area) witnessed an enhanced current density value 12.46 mA/cm(2) and power conversion efficiency (PCE) 4.84% is higher than the normal PE based f-DSSC (11.56 mA/cm(2) and 4.35%). For comparison, platinum-based f-DSSC with SM-PE is fabricated, is attained 6.08% of PCE. The f-DSSC sub-module with MoS2-CE gave 4.21% of PCE, the results are presented.
引用
收藏
页码:447 / 452
页数:6
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