An Unusual Mercury(II) Diisopropyldithiocarbamate Coordination Polymer

被引：16

作者：

Angeloski, Alexander ^{[1
]}

Rawal, Aditya ^{[2
]}

Bhadbhade, Mohan ^{[3
]}

Hook, James M. ^{[2
,3
]}

Schurko, Robert W. ^{[4
]}

Mcdonagh, Andrew M. ^{[1
]}

机构：

[1] Univ Technol Sydney, Sch Math & Phys Sci, Ultimo 2007, Australia

[2] Univ New South Wales, NMR Facil, Mark Wainwright Analyt Ctr, Sydney, NSW 2052, Australia

[3] Univ New South Wales, Sch Chem, Sydney, NSW 2052, Australia

[4] Univ Windsor, Dept Chem & Biochem, Windsor, ON N9B 3P4, Canada

来源：

CRYSTAL GROWTH & DESIGN | 2019年 / 19卷 / 02期

基金：

加拿大自然科学与工程研究理事会;

关键词：

NICKEL SULFIDE NANOPARTICLES; SOLID-STATE NMR; CRYSTAL-STRUCTURE; DITHIOCARBAMATE COMPLEXES; MAS NMR; THERMAL-DECOMPOSITION; HG(II) COMPLEXES; RAY-DIFFRACTION; C-13; NMR; PRECURSORS;

D O I：

10.1021/acs.cgd.8b01619

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new polymeric mercury(II) diisopropyldithiocarbamate complex was synthesized by the reaction of sodium diisopropyldithiocarbamate with excess HgCl2 in water. The precise structure of the new compound was determined by single-crystal X-ray diffraction. A similar reaction, using a stoichiometric excess of the ligand, yielded the known monomeric bis(diisopropyldithiocarbamato)mercury(II) complex. The complexes could not be distinguished from each other by their solution-phase NMR spectra or their FTIR spectra. Solid-state NMR spectroscopy (Hg-199 and C-13) provided unambiguous data and showed that the monomeric complex and polymeric complex do not interconvert in solution or during crystal growth. Thermogravimetric experiments revealed quite different thermal decomposition behavior between the two compounds.

引用

页码：1125 / 1133

页数：9

共 68 条

[1] Group 12 dithiocarbamate complexes: Synthesis, characterization, and X-ray crystal structures of Zn(II) and Hg(II) complexes and their use as precursors for metal sulfide nanoparticles [J].

Ajibade, Peter A. ;

Mbese, Johannes Z. ;

Omondi, Bernard .

INORGANIC AND NANO-METAL CHEMISTRY, 2017, 47 (02) :202-212

[2] Transition metal dichalcogenide materials: Solid-state reaction synthesis of nanocrystalline nickel disulfide [J].

An, Gaojun ;

Liu, Chenguang ;

Hou, Yuandong ;

Zhang, Xiaoling ;

Liu, Yunqi .

MATERIALS LETTERS, 2008, 62 (17-18) :2643-2646

[3] Metal complexes of alkyl-aryl dithiocarbamates: Structural studies, anticancer potentials and applications as precursors for semiconductor nanocrystals [J].

Andrew, Fartisincha P. ;

Ajibade, Peter A. .

JOURNAL OF MOLECULAR STRUCTURE, 2018, 1155 :843-855

[4] From Lead(II) Dithiocarbamate Precursors to a Fast Response PbS Positive Temperature Coefficient Thermistor [J].

Angeloski, Alexander ;

Gentle, Angus R. ;

Scott, John A. ;

Cortie, Michael B. ;

Hook, James M. ;

Westerhausen, Mika T. ;

Bhadbhade, Mohan ;

Baker, Anthony T. ;

McDonagh, Andrew M. .

INORGANIC CHEMISTRY, 2018, 57 (04) :2132-2140

[5] Intramolecular H•••S interactions in metal di-(isopropyl)dithiocarbamate complexes [J].

Angeloski, Alexander ;

Hook, James M. ;

Bhadbhade, Mohan ;

Baker, Anthony T. ;

McDonagh, Andrew M. .

CRYSTENGCOMM, 2016, 18 (37) :7070-7077

[6] Bis(κ2S,S′-di(isopropyl)dithiocarbamato)nickel(II): Anagostic C-H•••Ni interactions and physical properties [J].

Angeloski, Alexander ;

Baker, Anthony Thomas ;

Bhadbhade, Mohan ;

McDonagh, Andrew Michael .

JOURNAL OF MOLECULAR STRUCTURE, 2016, 1113 :127-132

[7] 3D-, 2D- and 1D-supramolecular structures of {Zn[S2CN(CH2CH2OH)R] 2}2 and their {Zn[S2CN(CH2CH2OH)R]2}2(4,4′-bipyridine) adducts for R = CH2CH2OH, Me or Et:: polymorphism and pseudo-polymorphism [J].

Benson, Ronald E. ;

Ellis, Carol A. ;

Lewis, Clairissa E. ;

Tiekink, Edward R. T. .

CRYSTENGCOMM, 2007, 9 (10) :930-940

[8] PREPARATION AND CHARACTERIZATION OF SOME 6-COORDINATE, 7-COORDINATE, AND 8-COORDINATE TITANIUM(IV) N,N-DIALKYLDITHIOCARBAMATES [J].

BHAT, AN ;

FAY, RC ;

LEWIS, DF ;

LINDMARK, AF ;

STRAUSS, SH .

INORGANIC CHEMISTRY, 1974, 13 (04) :886-892

[9] Synthesis, characterization and dynamic stereochemistry of thermochromic tris(dithiocarbamato)vanadium(III) complexes [J].

Bhattacharya, S ;

Kanungo, BK ;

Sahoo, S .

JOURNAL OF COORDINATION CHEMISTRY, 2006, 59 (04) :371-378

[10] AN UNEXPECTED STOICHIOMETRIC EFFECT IN BOTH SOLUTION AND SOLID-STATE IN MERCURY-RICH DITHIOCARBAMATE CATION CHEMISTRY - CRYSTAL AND MOLECULAR-STRUCTURE OF POLYMERIC TRIS(PIPERIDINECARBODITHIOATO)DIMERCURY(II) PERCHLORATE [J].

BOND, AM ;

COLTON, R ;

HOLLENKAMP, AF ;

HOSKINS, BF ;

MCGREGOR, K ;

TIEKINK, ERT .

INORGANIC CHEMISTRY, 1991, 30 (02) :192-197

← 1 2 3 4 5 6 7 →