Recyclable Catalysts for Palladium-Catalyzed Aminations of Aryl Halides

被引:45
|
作者
Dumrath, Andreas [1 ]
Luebbe, Christa [1 ]
Neumann, Helfried [1 ]
Jackstell, Ralf [1 ]
Beller, Matthias [1 ]
机构
[1] Univ Rostock, Leibniz Inst Katalyse eV, D-18059 Rostock, Germany
关键词
amination; anilines; imidazolium ligands; palladium; phosphane ligands; CROSS-COUPLING REACTIONS; TRANSITION-METAL; PRIMARY AMINES; REDUCTIVE AMINATION; 2-PHASE CATALYSIS; GENERAL-SYNTHESIS; C-N; HETEROARYL BROMIDES; OXIDATIVE ADDITION; ROOM-TEMPERATURE;
D O I
10.1002/chem.201100984
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Aminated and recycled: Palladium/imidazolium phosphane catalysts enable efficient and general aminations of aryl halides, including direct amination with ammonia. Subsequent recycling is possible without any additional heterogenization (see scheme). © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码:9599 / 9604
页数:6
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