Recyclable Catalysts for Palladium-Catalyzed Aminations of Aryl Halides

被引：45
|
作者：
Dumrath, Andreas [1 ]
Luebbe, Christa [1 ]
Neumann, Helfried [1 ]
Jackstell, Ralf [1 ]
Beller, Matthias [1 ]
机构：
[1] Univ Rostock, Leibniz Inst Katalyse eV, D-18059 Rostock, Germany
来源：
CHEMISTRY-A EUROPEAN JOURNAL | 2011年 / 17卷 / 35期
关键词：
amination; anilines; imidazolium ligands; palladium; phosphane ligands; CROSS-COUPLING REACTIONS; TRANSITION-METAL; PRIMARY AMINES; REDUCTIVE AMINATION; 2-PHASE CATALYSIS; GENERAL-SYNTHESIS; C-N; HETEROARYL BROMIDES; OXIDATIVE ADDITION; ROOM-TEMPERATURE;
D O I：
10.1002/chem.201100984
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Aminated and recycled: Palladium/imidazolium phosphane catalysts enable efficient and general aminations of aryl halides, including direct amination with ammonia. Subsequent recycling is possible without any additional heterogenization (see scheme). © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：9599 / 9604
页数：6
相关论文
共 50 条
  • [1] A General Palladium-Catalyzed Amination of Aryl Halides with Ammonia
    Schulz, Thomas
    Torborg, Christian
    Enthaler, Stephan
    Schaeffner, Benjamin
    Dumrath, Andreas
    Spannenberg, Anke
    Neumann, Helfried
    Boerner, Armin
    Beller, Matthias
    CHEMISTRY-A EUROPEAN JOURNAL, 2009, 15 (18) : 4528 - 4533
  • [2] Palladium-catalyzed multiple aryl aminations of polybromobenzenes
    Witulski, B
    Senft, S
    Thum, A
    SYNLETT, 1998, (05) : 504 - +
  • [3] Progress in Palladium-Catalyzed Amination of Aryl Halides
    Fang, Shai
    Lu, Meixiang
    Long, Yuhua
    Yang, Diangqiao
    CHINESE JOURNAL OF ORGANIC CHEMISTRY, 2011, 31 (10) : 1573 - 1581
  • [4] Palladium-Catalyzed Monoarylation of Aryl Amine with Aryl Tosylates
    Xie, Xiaomin
    Ni, Gang
    Ma, Fangfang
    Ding, Lina
    Xu, Sheng
    Zhang, Zhaoguo
    SYNLETT, 2011, (07) : 955 - 958
  • [5] Progress in palladium-catalyzed amination of aryl halides
    Liu, P
    Li, SH
    Li, LM
    Wang, XR
    Yin, YQ
    Zhang, YH
    PROGRESS IN CHEMISTRY, 2005, 17 (02) : 286 - 292
  • [6] General and efficient palladium-catalyzed aminations of aryl chlorides
    Bei, XH
    Guram, AS
    Turner, HW
    Weinberg, WH
    TETRAHEDRON LETTERS, 1999, 40 (07) : 1237 - 1240
  • [7] Palladium-Catalyzed Hydroxylation of Aryl Halides under Ambient Conditions
    Sergeev, Alexey G.
    Schulz, Thomas
    Torborg, Christian
    Spannenberg, Anke
    Neumann, Helfried
    Beller, Matthias
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (41) : 7595 - 7599
  • [8] Selective Palladium-Catalyzed Aminocarbonylation of Aryl Halides with CO and Ammonia
    Wu, Xiao-Feng
    Neumann, Helfried
    Beller, Matthias
    CHEMISTRY-A EUROPEAN JOURNAL, 2010, 16 (32) : 9750 - 9753
  • [9] A Highly Active Ylide-Functionalized Phosphine for Palladium-Catalyzed Aminations of Aryl Chlorides
    Weber, Philip
    Scherpf, Thorsten
    Rodstein, Ilja
    Lichte, Dominik
    Schar, Lennart T.
    Goossen, Lukas J.
    Gessner, Viktoria H.
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2019, 58 (10) : 3203 - 3207
  • [10] Industrial-scale palladium-catalyzed coupling of aryl halides and amines - A personal account
    Buchwald, SL
    Mauger, C
    Mignani, G
    Scholz, U
    ADVANCED SYNTHESIS & CATALYSIS, 2006, 348 (1-2) : 23 - 39
12345