Catalyst-free rapid conversion of arylboronic acids to phenols under green condition

被引：1

作者：

Dong, Zhenhua ^{[1
]}

Pan, Hongguo ^{[1
]}

Liu, Mengmeng ^{[1
]}

机构：

[1] Henan Univ Technol, Coll Chem & Chem Engn, Lianhua St 100, Zhengzhou 450001, Peoples R China

来源：

ARKIVOC | 2021年

关键词：

Arylboronic acid; phenol; oxidation; catalyst-free; hydrogen peroxide; ARYL BORONIC ACIDS; IPSO-HYDROXYLATION; ASYMMETRIC DEAROMATIZATION; METAL; NANOPARTICLES; ACCESS; WATER;

D O I：

10.24820/ark.5550190.p011.588

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A catalyst-free and solvent-free method for the oxidative hydroxylation of aryl boronic acids to corresponding phenols with hydrogen peroxide as the oxidizing agent was developed. The reactions could be performed under green condition at room temperature within very short reaction time. 99% yield of phenol could be achieved in only 1 min. A series of different arenes substituted aryl boronic acids were further carried out in the hydroxylation reaction with excellent yield. It was worth nothing that the reaction could completed within 1 min in all cases in the presence of ethanol as co-solvent. [GRAPHICS] .

引用

页码：324 / 330

页数：7

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