Highly Regio- and Diastereoselective Anionic [3+2] Cycloaddition under Phase Transfer Catalytic Conditions

被引：23

作者：

Gembus, Vincent

Postikova, Svetlana

Levacher, Vincent

Briere, Jean-Francois ^{[1
]}

机构：

[1] Univ Rouen, CNRS, UMR, COBRA, F-76821 Mont St Aignan, France

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2011年 / 76卷 / 10期

关键词：

CYCLIZATION-ELIMINATION ROUTE; CYCLOPENTENYL SULFONES; CONSTRUCTION; UNITS;

D O I：

10.1021/jo2005268

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A highly trans and regioselective anionic formal [3 + 2] cycloaddition was achieved with allylic sulfones having an MBH acrylamide backbone under phase transfer organocatalytic conditions giving rise to the formation of unprecedented densely substituted cyclopentene derivatives.

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收藏

页码：4194 / 4199

页数：6

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