Corrosion behavior of alumina ceramics in aqueous HCl and H2SO4 solutions

被引:50
作者
Curkovic, Lidija [1 ]
Jelaca, Mirjana Fuduric
Kurajica, Stanislav [2 ]
机构
[1] Univ Zagreb, Fac Mech Engn & Naval Architecture, HR-10002 Zagreb, Croatia
[2] Univ Zagreb, Fac Chem Engn & Technol, HR-10002 Zagreb, Croatia
关键词
ceramic; acid corrosion; kinetic parameters;
D O I
10.1016/j.corsci.2007.10.008
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The corrosion behavior of cold isostatically pressed (CIP) high purity alumina ceramics in aqueous HCl and H2SO4 solutions with various concentrations has been studied simultaneously at room temperature (25 degrees C). Corrosion tests were also performed with 0.65 mol/ 1 HCl and 0.37 mol/1 H2SO4 solutions at 40, 55 and 70 degrees C for 48 h. Chemical stability was monitored by determining the amount of Al3+, Mg2+, Ca2+, Na+ Si4+ and Fe3+ ions eluted in different concentrations of HCl and H2SO4 solutions by means of atomic absorption spectrometry (AAS). By increasing the concentration from 0.37 to 6.5 mol/l, it was notified that the corrosion susceptibility in HCl and H2SO4 solutions for the CIP alumina specimens at room temperature decreases. (C) 2007 Elsevier Ltd. All rights reserved.
引用
收藏
页码:872 / 878
页数:7
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