Dual fluorescent labelling of cellulose nanocrystals for pH sensing

被引:182
作者
Nielsen, Lise Junker [3 ]
Eyley, Samuel [1 ,2 ]
Thielemans, Wim [1 ,2 ]
Aylott, Jonathan W. [4 ]
机构
[1] Univ Nottingham, Sch Chem, Nottingham NG7 2RD, England
[2] Univ Nottingham, Proc & Environm Res Div, Fac Engn, Nottingham NG7 2RD, England
[3] Univ So Denmark, Dept Biochem & Mol Biol, DK-5230 Odense M, Denmark
[4] Univ Nottingham, Sch Pharm, Nottingham NG7 2RD, England
基金
英国工程与自然科学研究理事会;
关键词
ABSORPTION;
D O I
10.1039/c0cc03470c
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Cellulose nanocrystals were converted into ratiometric pH-sensing nanoparticles by dual fluorescent labelling employing a facile one-pot procedure. A simple and versatile three-step procedure was also demonstrated extending the number of fluorophores available for grafting. In this method an amine group was introduced via esterification followed by a thiol-ene click reaction.
引用
收藏
页码:8929 / 8931
页数:3
相关论文
共 21 条
[1]   Optical nanosensors - an enabling technology for intracellular measurements [J].
Aylott, JW .
ANALYST, 2003, 128 (04) :309-312
[2]   Nanotechnology applications in pollution sensing and degradation in agriculture: a review [J].
Baruah, Sunandan ;
Dutta, Joydeep .
ENVIRONMENTAL CHEMISTRY LETTERS, 2009, 7 (03) :191-204
[3]   Thin-film modified electrodes with reconstituted cellulose-PDDAC films for the accumulation and detection of triclosan [J].
Bonne, Michael J. ;
Edler, Karen J. ;
Buchanan, J. Grant ;
Wolverson, Daniel ;
Psillakis, Elefteria ;
Helton, Matthew ;
Thielemans, Wim ;
Marken, Frank .
JOURNAL OF PHYSICAL CHEMISTRY C, 2008, 112 (07) :2660-2666
[4]   Fluorescently labeled cellulose nanocrystals for bioimaging applications [J].
Dong, Shuping ;
Roman, Maren .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (45) :13810-+
[5]   Review: current international research into cellulose nanofibres and nanocomposites [J].
Eichhorn, S. J. ;
Dufresne, A. ;
Aranguren, M. ;
Marcovich, N. E. ;
Capadona, J. R. ;
Rowan, S. J. ;
Weder, C. ;
Thielemans, W. ;
Roman, M. ;
Renneckar, S. ;
Gindl, W. ;
Veigel, S. ;
Keckes, J. ;
Yano, H. ;
Abe, K. ;
Nogi, M. ;
Nakagaito, A. N. ;
Mangalam, A. ;
Simonsen, J. ;
Benight, A. S. ;
Bismarck, A. ;
Berglund, L. A. ;
Peijs, T. .
JOURNAL OF MATERIALS SCIENCE, 2010, 45 (01) :1-33
[6]   Ultraviolet visible absorption, luminescence, and X-ray photoelectron spectroscopic studies of a rhodamine dye covalently bound to microcrystalline cellulose [J].
Ferreira, LFV ;
Cabral, PV ;
Almeida, P ;
Oliveira, AS ;
Reis, MJ ;
do Rego, AMB .
MACROMOLECULES, 1998, 31 (12) :3936-3944
[7]   Fluorescent cellulose microfibrils as substrate for the detection of cellulase activity [J].
Helbert, W ;
Chanzy, H ;
Husum, TL ;
Schülein, M ;
Ernst, S .
BIOMACROMOLECULES, 2003, 4 (03) :481-487
[8]   Thiol-Ene Click Chemistry [J].
Hoyle, Charles E. ;
Bowman, Christopher N. .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2010, 49 (09) :1540-1573
[9]   The role of nanobiotechnology in drug discovery [J].
Jain, KK .
DRUG DISCOVERY TODAY, 2005, 10 (21) :1435-1442
[10]   Thiol-ene "click" reactions and recent applications in polymer and materials synthesis [J].
Lowe, Andrew B. .
POLYMER CHEMISTRY, 2010, 1 (01) :17-36