Enantioselective rhodium(I)-catalyzed hydrogenation of trifluoromethyl ketones

被引：54
|
作者：
Kuroki, Y [1 ]
Sakamaki, Y [1 ]
Iseki, K [1 ]
机构：
[1] Daikin Ind Ltd, Div Chem, Tsukuba, Ibaraki 3050841, Japan
来源：
ORGANIC LETTERS | 2001年 / 3卷 / 03期
关键词：
D O I：
10.1021/ol006962s
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
[GRAPHICS] The asymmetric hydrogenation of trifluoromethyl ketones to yield chiral alpha -trifluoromethyl alcohols with enantiomeric excesses up to 98% was achieved in the presence of chiral rhodium-(amidephosphine-phosphinite) complexes.
引用
收藏
页码：457 / 459
页数：3
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