Synthesis and structure of a two-dimensional copper(II) coordination polymer with 3,4,9,10-perylenetetracarboxylic acid and ethylenediamine

被引：10

作者：

Suenaga, Y ^{[1
]}

Kuroda-Sowa, T

Munakata, M

Maekawa, M

机构：

[1] Kinki Univ, Dept Chem, Higashiosaka, Osaka 577, Japan

[2] Kinki Univ, Sci & Technol Res Inst, Higashiosaka, Osaka 577, Japan

来源：

POLYHEDRON | 1998年 / 17卷 / 13-14期

关键词：

copper(II) complex; 3,4,9,10-perylenetetracarboxylic acid; ethylenediamine; hydrogen-bonding network;

D O I：

10.1016/S0277-5387(98)00043-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The crystal and molecular structure of a dinuclear copper(II) complex with 3,4,9,10-perylenetetracarboxylic acid (H(4)ptca) and ethylenediamine (en) [Cu-2(en)(4)(mu-ptca)] (EtOH)(2)(H2O)(6) has been determined by X-ray structural analysis. Each copper atom is coordinated by four-nitrogen atoms of two en molecules, one oxygen atom of bridging ptca(4-) and one water molecule in an octahedral arrangement. The resulting dinuclear copper(II) complex forms two-dimensional network through intermolecular hydrogen bonds between carboxylate of ptca4- and the water. (C) 1998 Elsevier Science Ltd; All rights reserved.

引用

页码：2207 / 2211

页数：5

共 13 条

[11] Synthesis and structure of a three-dimensional lanthanum(III) coordination polymer with mellitate, {La-2[C-6(COO)(6)](H2O)(9)}.2H(2)O [J].