A solar tower fuel plant for the thermochemical production of kerosene from H2O and CO2

Developing solar technologies for producing carbon-neutral aviation fuels has become a global energy challenge, but their readiness level has largely been limited to laboratory-scale studies. Here, we report on the experimental demonstration of a fully integrated thermochemical production chain from H2O and CO2 to kerosene using concentrated solar energy in a solar tower configuration. The cosplitting of H2O and CO2 was performed via a ceria-based thermochemical redox cycle to produce a tailored mixture of H-2 and CO (syngas) with full selectivity, which was further processed to kerosene. The 50-kW solar reactor consisted of a cavity-receiver containing a reticulated porous structure directly exposed to a mean solar flux concentration of 2,500 suns. A solar-to-syngas energy conversion efficiency of 4.1% was achieved without applying heat recovery. This solar tower fuel plant was operated with a setup relevant to industrial implementation, setting a technological milestone toward the production of sustainable aviation fuels.