Selective Dimerization of Aryl-substituted Terminal Alkynes on Bis(indenyl)zirconocene Derivatives

被引：7

作者：

Ren, Shenyong ^{[1
,2
,3
]}

Seki, Takashi ^{[4
]}

Necas, David ^{[1
,2
,3
]}

Shimizu, Hiroyuki ^{[5
]}

Nakajima, Kiyohiko ^{[6
]}

Kanno, Ken-ichiro ^{[1
,2
,3
]}

Song, Zhiying ^{[1
,2
,3
]}

Takahashi, Tamotsu ^{[1
,2
,3
]}

机构：

[1] Hokkaido Univ, Catalysis Res Ctr, Kita Ku, Sapporo, Hokkaido 0010021, Japan

[2] Hokkaido Univ, Grad Sch Pharmaceut Sci, Kita Ku, Sapporo, Hokkaido 0600812, Japan

[3] Japan Sci & Technol Agcy JST, SORST, Chiyoda Ku, Tokyo 1020075, Japan

[4] JX Nippon Oil & Energy Corp, Naka Ku, Yokohama, Kanagawa 2310815, Japan

[5] Japan Polyethylene Corp, Kawasaki Ku, Kawasaki, Kanagawa 2100865, Japan

[6] Aichi Univ Educ, Dept Chem, Kariya, Aichi 4488542, Japan

来源：

CHEMISTRY LETTERS | 2011年 / 40卷 / 12期

关键词：

INDENYL COMPLEXES; BENZENE-DERIVATIVES; COUPLING REACTIONS; RING-SLIPPAGE; CYCLOADDITION; ACETYLENES; REACTIVITY; CONVERSION; CHEMISTRY; ZIRCONACYCLOPENTADIENES;

D O I：

10.1246/cl.2011.1443

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Dimerization of aryl-substituted terminal alkynes on indenyl zirconium complexes occurred in a selective way. 1,4-Aryl-1,3-diene derivatives were formed exclusively after hydrolysis. It is in sharp contrast to the reaction on [Cp2Zr] complexes.

引用

页码：1443 / 1444

页数：2

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