Charge transfer complexes of electron-rich naphthalene peri-dichalcogenides with TCNQ

被引：6
作者：
Press, David J. [1 ]
Back, Thomas G. [1 ]
Sutherland, Todd C. [1 ]
机构：
[1] Univ Calgary, Dept Chem, Calgary, AB T2N 1N4, Canada
来源：
TETRAHEDRON LETTERS | 2012年 / 53卷 / 13期
基金：
加拿大自然科学与工程研究理事会;
关键词：
Chalcogens; Charge transfer complex; UV-vis spectroscopy; Cyclic voltammetry; TETRATHIAFULVALENES; DERIVATIVES;
D O I：
10.1016/j.tetlet.2012.01.068
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The electronic structures of several highly electron-rich 2,7-dimethoxynaphthalene peri-dichalcogenides were evaluated using optical and electrochemical methods, as well as by DFT calculations. Charge transfer complexes were formed with tetracyanoquinodimethane and resulted in absorption features that span from 300 nm to 1600 nm and HOMO-LUMO energy gaps as low as 0.8 eV. (C) 2012 Elsevier Ltd. All rights reserved.
引用
收藏
页码：1603 / 1605
页数：3
相关论文
共 27 条
  • [21] Enhanced electron cloud through π-π interaction in charge-transfer complexes for all-solid-state lithium batteries
    Song, Fengmei
    Wang, Zhixuan
    Ma, Tenghuan
    Chen, Liquan
    Li, Hong
    Wu, Fan
    NANO ENERGY, 2023, 117
  • [22] UV-Vis, IR spectra and thermal studies of charge transfer complexes formed in the reaction of 4-benzylpiperidine with σ- and π-electron acceptors
    Mostafa, Adel
    El-Ghossein, Nada
    Cieslinski, G. Benjamin
    Bazzi, Hassan S.
    JOURNAL OF MOLECULAR STRUCTURE, 2013, 1054 : 199 - 208
  • [23] Electrochemical and spectrophotometrical investigation of the electron-accepting strength of organic superelectrophiles: X-ray structure of their charge transfer complexes with tetrathiafulvalene
    Berionni, Guillaume
    Goncalves, Anne-Marie
    Mathieu, Charles
    Devic, Thomas
    Etcheberry, Arnaud
    Goumont, Regis
    PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2011, 13 (07) : 2857 - 2869
  • [24] New Charge-Transfer Complexes with 1,2,5-Thiadiazoles as Both Electron Acceptors and Donors Featuring an Unprecedented Addition Reaction
    Chulanova, Elena A.
    Pritchina, Elena A.
    Malaspina, Lorraine A.
    Grabowsky, Simon
    Mostaghimi, Farzin
    Beckmann, Jens
    Bagryanskaya, Irina Yu.
    Shakhova, Margarita V.
    Konstantinova, Lidia S.
    Rakitin, Oleg A.
    Gritsan, Nina P.
    Zibarev, Andrey V.
    CHEMISTRY-A EUROPEAN JOURNAL, 2017, 23 (04) : 852 - 864
  • [25] Triphenylene-Derived Electron Acceptors and Donors on Ag(111): Formation of Intermolecular Charge-Transfer Complexes with Common Unoccupied Molecular States
    Mueller, Kathrin
    Schmidt, Nico
    Link, Stefan
    Riedel, Rene
    Bock, Julian
    Malone, Walter
    Lasri, Karima
    Kara, Abdelkader
    Starke, Ulrich
    Kivala, Milan
    Stohr, Meike
    SMALL, 2019, 15 (33)
  • [26] Spectrophotometric Investigations of Charge Transfer Complexes of Tyrosine Kinase Inhibitors with Iodine as a σ-Electron Acceptor: Application to Development of Universal High-Throughput Microwell Assay for Their Determination in Pharmaceutical Formulations
    Darwish, Ibrahim A.
    Darwish, Hany W.
    Ali, Awadh M.
    Almutairi, Halah S.
    MEDICINA-LITHUANIA, 2023, 59 (04):
  • [27] Exclusive formation of 1:1 and 2:2 complexes between cucurbit[8]uril and electron donor-acceptor molecules induced by host-stabilized charge-transfer interactions
    Ko, Young Ho
    Kim, Kyungpil
    Kim, Eunju
    Kim, Kimoon
    SUPRAMOLECULAR CHEMISTRY, 2007, 19 (4-5) : 287 - 293
123