Pressure-induced crystallization of amorphous red phosphorus

被引：61

作者：

Rissi, Erin N. ^{[1
]}

Soignard, Emmanuel ^{[1
,2
]}

McKiernan, Keri A. ^{[1
]}

Benmore, Chris J. ^{[3
,4
]}

Yarger, Jeffery L. ^{[1
,4
]}

机构：

[1] Arizona State Univ, Dept Chem & Biochem, Tempe, AZ 85287 USA

[2] Arizona State Univ, LeRoy Eyring Ctr Solid State Sci, Tempe, AZ 85287 USA

[3] Argonne Natl Lab, Adv Photon Source, Xray Sci Div, Argonne, IL 60439 USA

[4] Arizona State Univ, Dept Phys, Tempe, AZ 85287 USA

来源：

SOLID STATE COMMUNICATIONS | 2012年 / 152卷 / 05期

关键词：

Disordered systems; Phase transitions; INTERMEDIATE-RANGE ORDER; BLACK PHOSPHORUS; CRYSTAL-STRUCTURE; RAMAN-SCATTERING; STABILITY; DIFFRACTION; RECOMBINATION;

D O I：

10.1016/j.ssc.2011.12.003

中图分类号：

O469 [凝聚态物理学];

学科分类号：

070205 ;

摘要：

Structural transitions in amorphous red phosphorus were studied at ambient temperature and pressures up to 12 GPa. Amorphous (red) phosphorus was observed to transform into crystalline black phosphorus at 7.5 +/- 0.5 GPa using diamond anvil cell Raman spectroscopy, x-ray diffraction and a direct equation of state (EoS) measurement. The transition was found to be irreversible and the material recovered upon pressure cycling to 10 to 12 GPa was crystalline orthorhombic black phosphorus. A third order Birch-Murnaghan EoS was fit to the data and a bulk modulus (B0) of 11.2 GPa was measured for amorphous red phosphorus. Published by Elsevier Ltd

引用

页码：390 / 394

页数：5

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