Photocatalytic activity of CdS nanoparticles synthesized by a facile composite molten salt method

被引:77
作者
Li, Xiaoyan [1 ]
Hu, Chenguo [1 ]
Wang, Xue [1 ]
Xi, Yi [1 ]
机构
[1] Chongqing Univ, Dept Appl Phys, Chongqing 400044, Peoples R China
关键词
CdS; Nanoparticles; Composite-molten-salt; Photodegradation; METHYLENE-BLUE; DEGRADATION; NANOWIRES; ARRAYS; FILMS;
D O I
10.1016/j.apsusc.2011.12.116
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Single-crystalline CdS nanoparticles were synthesized for the first time by the composite-molten-salt (CMS) method, with advantages of one-step, ambient pressure, low temperature, template-free and low cost. The influence of temperature, growth time and amount of salts on the morphology of CdS nanoparticles was systematically investigated. It shows that a smaller size of CdS nanoparticles can be obtained under lower temperature, less growth time and more composite salts. UV-vis reflection spectrum of the nanoparticles reveals that the nanoparticles have a bandgap of 2.34 eV. Photoluminescence spectrum was also carried out to explore its optical property. Photocatalytic degradation of rhodamine B (RhB) and methylene blue (MB) in presence of the CdS nanoparticles was compared with that in presence of the commercial TiO2 nanoparticles under the simulated sunlight. (C) 2012 Elsevier B.V. All rights reserved.
引用
收藏
页码:4370 / 4376
页数:7
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