Holmium complex with phospholipids as 1H NMR temperature probe for membrane systems

被引：5

作者：

Selyutina, O. Yu ^{[1
]}

Koshman, V. E. ^{[1
]}

Zelikman, M., V ^{[2
]}

Babailov, S. P. ^{[3
]}

机构：

[1] Inst Chem Kinet & Combust, Inst Skaya St 3, Novosibirsk 630090, Russia

[2] Inst Solid State Chem & Mechanochem, Kutateladze St 18, Novosibirsk, Russia

[3] Russian Acad Sci, Siberian Branch, AV Nikolaev Inst Inorgan Chem, Av Lavrentyev 3, Novosibirsk 630090, Russia

来源：

BIOMETALS | 2022年 / 35卷 / 03期

基金：

俄罗斯科学基金会;

关键词：

Lanthanides; Lipid membrane; NMR; Membrane temperature sensor; Paramagnetic shift; FAST MOLECULAR-DYNAMICS; MAGNETIC-RESONANCE; LANTHANIDE COMPLEXES; CONFORMATIONAL DYNAMICS; PARAMAGNETIC PROBE; NMR; ETHYLENEDIAMINETETRAACETATE; PRASEODYMIUM; CONJUNCTION; LIPOSOMES;

D O I：

10.1007/s10534-022-00388-3

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

The temperature dependence of the lanthanide-induced chemical shifts (LISs) was studied for the systems containing 1-palmitoyl-2-oleoylphosphatidylcholine (POPC)-Ho, 1,2-dipalmitoyl-sn-glycero-3-phosphocholine (DPPC)-Ho and 1,2-dimyristoyl-sn-glycero-3-phosphorylcholine (DMPC)-Ho in unilamellar liposomes. In the POPC-Ho system, anti-Curie dependence of LISs is observed, same as previously observed in POPC-Pr system. In the DPPC- and DMPC-Ho systems, temperature features are observed which are probably connected with phase transition.

引用

页码：629 / 637

页数：9

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