Synthesis, crystal structure and magnetic property of a new layered copper(II) complex with picolinic acid N-oxide built from Cu2O2 dimer units

被引：8
|
作者：
Yang, BP
Mao, JG [1 ]
Dong, ZC
机构：
[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China
[2] Natl Inst Mat Sci, Tsukuba, Ibaraki 3050047, Japan
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2004年 / 7卷 / 01期
关键词：
copper complex; crystal structure; Cu2O2; dimer; layered compound; magnetic property;
D O I：
10.1016/j.inoche.2003.10.018
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Reaction of copper(II) chloride with picolinic acid N-oxide (HL) in acetone/THF mixed solvent afforded a novel layered compound, [Cu(L)Cl(H2O)](2), in which each pair of octahedrally coordinated copper(II) ions are bridged by two N-oxide groups to form a Cu2O2 dimeric unit, and such dimeric units are further interconnected via carboxylate groups to form a layer. (C) 2003 Elsevier B.V. All rights reserved.
引用
收藏
页码：104 / 106
页数：3
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